 |
 |
 |
 |
 |
 |
||
 |
 |
 |
 |
 |
| 5 | 1/1 | 返回列表 |
| 查看: 747 | 回復(fù): 5 | |||
| 本帖產(chǎn)生 1 個 翻譯EPI ，點(diǎn)擊這里進(jìn)行查看 | |||
| 當(dāng)前只顯示滿足指定條件的回帖，點(diǎn)擊這里查看本話題的所有回帖 | |||
[求助]
中譯英，一句話
|
|||
| 為了更好的得到反映配合物1內(nèi)磁耦合實(shí)際情況的主要參數(shù)，而又不使體系過于復(fù)雜化，在仔細(xì)分析該配合物晶體結(jié)構(gòu)參數(shù)的基礎(chǔ)上，并參考一些相關(guān)的磁與結(jié)構(gòu)關(guān)系的文獻(xiàn)報道，導(dǎo)出更加合理磁耦合模型。 |
回復(fù)此樓» 猜你喜歡
262求調(diào)劑
已經(jīng)有5人回復(fù)
-
0856調(diào)劑
已經(jīng)有6人回復(fù)
-
張芳銘-中國農(nóng)業(yè)大學(xué)-環(huán)境工程專碩-298
已經(jīng)有6人回復(fù)
-
考研生物與醫(yī)藥調(diào)劑
已經(jīng)有3人回復(fù)
-
274求調(diào)劑
已經(jīng)有5人回復(fù)
-
化學(xué)工程085602 305分求調(diào)劑
已經(jīng)有26人回復(fù)
-
334求調(diào)劑
已經(jīng)有3人回復(fù)
-
一志愿 南京航空航天大學(xué) ，080500材料科學(xué)與工程學(xué)碩
已經(jīng)有5人回復(fù)
-
看看我！301求調(diào)劑 081700
已經(jīng)有3人回復(fù)
-
求調(diào)劑 生物學(xué) 377分
已經(jīng)有3人回復(fù)
【答案】應(yīng)助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
zyxr: 金幣+20, 翻譯EPI+1, ★★★★★最佳答案 2014-01-11 21:17:24
zyxr: 金幣+20, 翻譯EPI+1, ★★★★★最佳答案 2014-01-11 21:17:24
|
Allow me make further polishing on the above translation. ... yet without over-complicating the system, we have carried out a very detailed analysis of.... ... , thus deriving an improved magnetic-coupling model. comment:很少會說a careful analysis, export沒有derive準(zhǔn)確。more reasonable model 有點(diǎn)詆毀別人的工作，我建議用improved會更容易讓人接受。 |
3樓2014-01-11 20:43:46
|
In order to obtain main parameters which can better reflect the actual situation of magnetic coupling in complex 1, without making the system too complicated, we carried out a very careful analysis of the crystal structure parameters and referred to some relevant magnetic and structural relationships reported in the literature [], exporting more reasonable magnetic coupling model. 請大家潤色 |
2樓2014-01-11 11:06:05
4樓2014-01-11 21:17:18
|
我追加了77 個金幣，希望能得到你指導(dǎo)啊，下面這段比較長哈。 根據(jù)配合物1的晶體結(jié)構(gòu)參數(shù)（圖2左），Mn(1)-O(2)-Mn(2)，Mn(3)-O(4)-Mn(2)和Mn(4)-O(8)-Mn(2)的鍵角很接近，可知Mn(1)，Mn(3), Mn(4)與Mn(2)之間的磁耦合常數(shù)J應(yīng)該很相近，假定它們相等是合理的（J1）。另外，Mn(1)-O(9)-Mn(3)的鍵角是139.5o，與其它鍵角差別較大，因此Mn(1)-Mn(3)之間的磁耦合也是必須考慮的一種情況（J2）。Mn(1)-O(9)-Mn(4)和Mn(3)-O(9)-Mn(4)的鍵角近似相等，并處于110o左右，根據(jù)文獻(xiàn)的報道結(jié)果，該鍵角所處的范圍導(dǎo)致Mn(III)-Mn(III)之間弱的鐵磁耦合，并且Mn(1)-Mn(4)之間還通過疊氮EO橋聯(lián)傳遞弱的鐵磁耦合，Mn(3)-Mn(4)之間也還存在一個Mn(3)-O(6)-Mn(4)磁耦合路線，該鍵角為92.1o，也應(yīng)該處在鐵磁耦合范圍內(nèi) According to the crystal structure parameters of complex 1 (right in fig 2), due to the bond angles of Mn(1)-O(2)-Mn(2)，Mn(3)-O(4)-Mn(2) and Mn(4)-O(8)-Mn(2) are close to each other, we can infer that the magnetic coupling constants have a quite modest differences between Mn(1)and Mn(2), Mn(3) and Mn(2), Mn(4) and Mn(2), hence, we hypothesize the same J1 between them is reasonable. In addition, the bond angle of Mn(1)-O(9)-Mn(3) is 139.5o obviously different with others, so the magnetic coupling between Mn(1) and Mn(3) is another situation should be considered (J2). The angles of Mn(1)-O(9)-Mn(4) and Mn(3)-O(9)-Mn(4) are approximately equal about 110o, based on the results of literature reports, the range of the bond angles result in a weak ferromagnetic coupling between Mn(III)-Mn(III), moreover Mn(1)-Mn(4) though azide EO bridging transmit weak ferromagnetic coupling, Mn(3)-Mn(4) also exist a Mn(3)-O(6)-Mn(4) magnetic coupling passway and the angle is 92.1o which should be in the range of ferromagnetic coupling. |
5樓2014-01-11 21:37:53
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 334求調(diào)劑 +3 | Trying] 2026-03-31 | 3/150 |
|
|---|---|---|---|---|
|
[考研] 學(xué)碩274求調(diào)劑 +14 | Li李魚 2026-03-26 | 14/700 |
|
|
|
[考研] 266分，求材料相關(guān)專業(yè)調(diào)劑 +8 | 哇呼哼呼哼 2026-03-30 | 10/500 |
|
|
|
[考研] 285求調(diào)劑 +6 | AZMK 2026-03-29 | 9/450 |
|
|
|
[考研] 一志愿北京化工大學(xué)材料與化工（085600）296求調(diào)劑 +25 | 稻妻小編 2026-03-26 | 25/1250 |
|
|
|
[考研] 一志愿南昌大學(xué)324求調(diào)劑 +9 | hanamiko 2026-03-27 | 9/450 |
|
|
|
[考研] 生物技術(shù)與工程 +7 | 1294608413 2026-03-25 | 8/400 |
|
|
|
[碩博家園] 招收生物學(xué)/細(xì)胞生物學(xué)調(diào)劑 +4 | IceGuo 2026-03-26 | 5/250 |
|
|
|
[考研] 320分，材料與化工專業(yè)，求調(diào)劑 +9 | 一定上岸aaa 2026-03-27 | 13/650 |
|
|
|
[考研] 材料與化工（0856）304求B區(qū)調(diào)劑 +8 | 邱gl 2026-03-27 | 8/400 |
|
|
|
[考研] 085701環(huán)境工程，267求調(diào)劑 +16 | minht 2026-03-26 | 16/800 |
|
|
|
[考研] 308求調(diào)劑 +7 | 墨墨漠 2026-03-27 | 7/350 |
|
|
|
[考研] 331環(huán)境科學(xué)與工程求調(diào)劑 +3 | 熠然好運(yùn)氣 2026-03-27 | 3/150 |
|
|
|
[考研] 化學(xué)調(diào)劑 +4 | 愛吃番茄的旭 2026-03-24 | 5/250 |
|
|
|
[考研]
 一志愿 西北大學(xué) 總分282 英語一62 求調(diào)劑
+7
|
18419759900 2026-03-25 | 8/400 |
|
|
|
[考研] 調(diào)劑求收留 +7 | 果然有我 2026-03-26 | 7/350 |
|
|
|
[考研] 求調(diào)劑 一志愿 本科 北科大 化學(xué) 343 +6 | 13831862839 2026-03-24 | 7/350 |
|
|
|
[考研] 321求調(diào)劑 +6 | Ymlll 2026-03-24 | 6/300 |
|
|
|
[考研] 材料與化工304求B區(qū)調(diào)劑 +3 | 邱gl 2026-03-25 | 3/150 |
|
|
|
[考研] 302求調(diào)劑 +4 | 錦衣衛(wèi)藤椒 2026-03-25 | 4/200 |
|