Poly(N-isopropylacrylamide) (variously abbreviated PNIPA, PNIPAAm, PNIPAA or PNIPAm) is a temperature-responsive polymer that was first synthesized in the 1950s.[1]
It forms a three-dimensional hydrogel when crosslinked with N,N’-methylene-bis-acrylamide (MBAm) or N,N’-cystamine-bis-acrylamide (CBAm). When heated in water above 33°C, it undergoes a reversible phase transition from a swollen hydrated state to a shrunken dehydrated state, losing about 90% of its mass. Since PNIPAm expels its liquid contents at a temperature near that of the human body, PNIPAm has been investigated by many researchers for possible applications in controlled drug delivery.[2][3]
不清楚,幫頂
自己做個(gè)DSC測(cè)吧,不同型號(hào)的有差別
聚N-異丙基丙烯酰胺單鏈附聚體的制備及玻璃化轉(zhuǎn)變行為的研究
2007年全國(guó)高分子學(xué)術(shù)論文報(bào)告會(huì)(2007.10.9-13 成都)
謝謝大家頂貼
最好自己做一下測(cè)試啊,因?yàn)椴煌木酆隙扔胁町惖,?0左右吧,可以用DSC,TG,DMA等測(cè)一下
Poly(N-isopropylacrylamide) (variously abbreviated PNIPA, PNIPAAm, PNIPAA or PNIPAm) is a temperature-responsive polymer that was first synthesized in the 1950s.[1]
It forms a three-dimensional hydrogel when crosslinked with N,N’-methylene-bis-acrylamide (MBAm) or N,N’-cystamine-bis-acrylamide (CBAm). When heated in water above 33°C, it undergoes a reversible phase transition from a swollen hydrated state to a shrunken dehydrated state, losing about 90% of its mass. Since PNIPAm expels its liquid contents at a temperature near that of the human body, PNIPAm has been investigated by many researchers for possible applications in controlled drug delivery.[2][3]
呵呵,英文不是很好,是不是說明玻璃化轉(zhuǎn)變溫度為33℃。繌木S基百科上找到的,不知道對(duì)不對(duì)哦^_^
https://en.wikipedia.org/wiki/Poly(N-isopropylacrylamide)
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