Thermal and Chemical Stability of DMSO
DMSO is highly stable at temperatures below 150° C. For example, holding DMSO at 150° C for 24 hours, one
could expect a loss of between 0.1 and 1.0%. Retention times even in batch stills are usually considerably less than this, and
therefore, losses would be correspondingly less.. It has been reported that only 3.7% of volatile materials are produced during 72
hours at the boiling point (189° C) of DMSO (1). Slightly more decomposition, however, can be expected with the industrial grade
material. Thus, about 5% DMSO decomposes at reflux after 24 hours (3921). Almost half of the weight of the volatile materials is
paraformaldehyde. Dimethyl sulfide, dimethyl disulfide, bis(methylthio)methane and water are other volatile products. A small amount
of dimethyl sulfone can also be found. The following sequence of reactions explains the formation of these decomposition
products
二甲硫醚?
好像是有刺激性的硫化物,具體的不知道
會不會是硫化氫H2S氣體啊?
復(fù)分解生成二甲硫醚和二甲基砜
Thermal and Chemical Stability of DMSO

DMSO is highly stable at temperatures below 150° C. For example, holding DMSO at 150° C for 24 hours, one
could expect a loss of between 0.1 and 1.0%. Retention times even in batch stills are usually considerably less than this, and
therefore, losses would be correspondingly less.. It has been reported that only 3.7% of volatile materials are produced during 72
hours at the boiling point (189° C) of DMSO (1). Slightly more decomposition, however, can be expected with the industrial grade
material. Thus, about 5% DMSO decomposes at reflux after 24 hours (3921). Almost half of the weight of the volatile materials is
paraformaldehyde. Dimethyl sulfide, dimethyl disulfide, bis(methylthio)methane and water are other volatile products. A small amount
of dimethyl sulfone can also be found. The following sequence of reactions explains the formation of these decomposition
products
[ Last edited by dgf2008 on 2010-4-7 at 10:40 ],
我曾經(jīng)加錯藥品,把二氯亞砜與DMSO混合,結(jié)果就產(chǎn)生了刺激性的氣體,爆鳴聲。我也知道是怎么回事,估計和這個相似。
謝謝各位蟲蟲的幫助,我明白了!