麓貿(mào)錄脪脭脵麓脦脨脗脛錨潞脙攏隆
脫毛脥霉脛錨脪祿脩霉攏盧陸帽脛錨路簍鹿煤虜簍露沒露脿麓貿(mào)脩摟碌脛CSC鹿蘆脜脡脫脰驢陋脢錄脕脣攏盧脭脵麓脦脢脺脰廬脟擄脜貿(mào)脫脩脦爐脥脨攏盧擄茂脳陋路壟脪脭脧脗2016脛錨碌脛PhD脮脨脜脝鹿茫賂忙 (Deadline: Feb 18th 2016攏盧碌蘆脢脟祿鹿脢脟戮隆脭莽脕陋脧碌脦陋潞脙攏盧鹵冒賂脧脭脷脳卯潞貿(mào)脪祿脤矛)攏盧脠莽鹿沒賂脨脨脣脠隴碌脛攏盧脟毛麓脫脣脵攏祿脧攏脥沒脫脨脰戮脕么路簍碌脛脜貿(mào)脫脩脙脟脛脺祿媒錄蘆脡錨脟毛攏盧虜簍露沒露脿虜?shù)摰撝櫭埫兠劽Ｃ兠嚸姄�脥沒攏盧:-)  脮芒賂枚脢脟路簍鹿煤脫毛csc碌脛鹿蘆脜脡脳簍脧卯攏盧脙驢脛錨icmcb露錄脛脺脛脙碌陸錄賂賂枚脙沒露卯攏盧脣霉脪脭脰祿脨貓脪陋脰鹵陸脫脕陋脧碌脌脧擄氓攏盧脠祿潞貿(mào)脳脽脧脗csc碌脛鹿脵路陸魯脤脨貌錄麓驢脡隆攏攏簍脫脨脨漏脨脜脧壟脪虜驢脡脪脭虜茅脭脛脦脪脰廬脟擄脠媒脛錨碌脛脤沒脳脫攏潞http://www.gaoyang168.com/bbs/viewthread.php?tid=6898912 潞脥 http://www.gaoyang168.com/bbs/viewthread.php?tid=5513969攏祿 http://www.gaoyang168.com/bbs/viewthread.php?tid=8383308攏漏

戮脽脤氓脡錨脟毛祿貌脮脽脳脡脩爐攏盧脟毛脰鹵陸脫脕陋脧碌 Prof. Corine MATHONIERE: corine.mathoniere@icmcb.cnrs.fr攏盧陸簍脪茅賂陸脡脧脛茫碌脛CV攏盧 brief summary of you education background, research experience, reserach interest, motivation letter, list of publication, list of referrences with detailed contact information, proof of good level of French or English language proficiency 脪脭錄擄脝盲脣沒脛茫戮玫碌脙脫脨脫脙碌脛脨脜脧壟隆攏陸脴脰脕脠脮脝脷 Feb. 18th 2016攏祿脭脵麓脦陸簍脪茅麓貿(mào)錄脪脭陸脭莽脕陋脧碌脭陸潞脙隆攏

路脟脩摟脢玫脦脢脤芒攏盧驢脡脪脭路壟脦脪脫脢錄鎂liujizgd@gmail.com祿貌脮脽脮戮脛脷脨脜攏盧脦脪戮隆脦脪脣霉脛脺祿脴賂麓脛茫脙脟隆攏

脮芒脌茂脦脪脣魯鹵茫脤霉魯枚ICMCB corine 驢脦脤芒脳茅碌脛脨脜脧壟攏盧https://sites.google.com/site/m3 ... s/corine-mathoniere攏盧 脕鉚脥芒賂陸錄鎂脌茂脙忙祿鹿脫脨脣媒碌脛賂枚脠脣cv攏盧脫脨脨脣脠隴碌脛驢脡脪脭脧脗脭脴驢麓脧脗隆攏

脪脭脧脗脢脟research proposal攏盧麓貿(mào)錄脪驢脡脪脭脥簍鹿媒脮芒脨漏脕脣陸芒脧脗戮脽脤氓碌脛驢脦脤芒路陸脧貌隆攏

CSC Ph Project proposed by Corine Mathoni簍簍re, University of Bordeaux.
Photomagnetic compounds based on [M(CN)8]4- building blocks M = Mo(IV) and W(IV)

The photoswitchable molecular compounds are an interesting class of materials because they can be used in data storage devices or sensors. In general, these systems have two (or more) distinct electronic states that can be addressed by temperature, visible light, pressure, electric field... When the two states have different magnetic behaviors, the systems are called photomagnetic compounds. Some of these photomagnetic systems are based on [M(CN)8]4- complexes linked to 3d metal ions and show an exceptional stability on their photo-induced states. Nevertheless, the electronic phenomenon at the origin of the photomagnetism in these systems is still a debate. Some studies affirm that an metal-metal electron transfer occurs between the [M(CN)8]4-and its 3d ionic neighbours,[1] and others propose a spin crossover in the [M(CN)8]4- unit.[2,3]

The proposed phD work consists of elucidating the mechanism responsible for the switching process in the [M(CN)8]4-/3d systems. The phD student will synthetize known and new compounds to have a large family of systems necessary for comparison and understanding of the photomagnetic properties. Then he(she) will study the photo-induced properties using different techniques: X-ray diffraction, spectroscopic measurements (IR, Raman, optical spectroscopy), cyclic voltammetry and magnetism. A special attention will be also devoted to the development of new systems with optimized switching properties. During the phD, measurements on synchrotron beamlines will be planned to perform local spectrocopies XANES and XMCD measurements in collaboration with the group of P. Sainctavit (Univ. Paris VI).

[1] J. M. Herrera, V. Marvaud, M. Verdaguer, J. Marrot, M. Kalisz, C. Mathoni簍簍re, Angew. Chem. Int. Ed., 2004, 43, 5468.
[2] M.-A. Arrio, J. Long, C. Cartier dit Moulin, A. Bachschmitt, V. Marvaud, A. Rogalev, C. Mathoni簍簍re, F. Wilhem, P. Sainctavit, J. Phys. Chem. C, 2010, 114, 593.
[3] O. Stefanczyk, A. M. Majcher, M. Rams, W. Nitek, C. Mathoni簍簍re, B. Sieklucka, J. Mater. Chem. C, 2015, 3, 8712.[ Last edited by liujizgd on 2016-1-26 at 20:05 ]

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