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kebochen061金蟲 (正式寫手)
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Each Eu cation is on the molecular 3-fold axis in a trigonally distorted octahedral coordination field, with one basal triangle being shared with a central [ Eu3(OH)3(OH2)3I4+ cluster and the other with an axial Nb anion. Each Eu atom achieves 8-fold coordination, with one terminal 0 atom, one 0 atom shared by three Eu atoms, two 0 atoms shared by two Eu atoms and one A1 atom, and four atoms of the equatorial [Nb6O19l8- anions, three of which are the p~(Nb2)-0 atoms of one [Nb6019I8- anion while the other is the terminal 0 atom of another [Nb6019I8- anion. |

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每個銪陽離子位于分子三角形扭曲的3重軸的八面體配位區(qū),其中一個基底三角與中央[Eu3(OH)3(OH2)3I4+配位基團共享,其他基底三角與軸向鈮陰離子共享。 每個銪原子8重配位,一個終端0原子,一個0原子由3 銪原子共享,2個銪原子和一個Al原子共享兩個0原子,四個赤道原子[Nb6O19l8-陰離子,其中3個為一[Nb6019I8陰離子的p~(Nb2)-0 原子 ,而另一個是的另一個[Nb6019I8陰離子的終端0原子。 cluster 配位基團 考慮到 (Cluster compounds 配位化合物),但不知翻對沒?自己再看看! |

金蟲 (正式寫手)

金蟲 (正式寫手)

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