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kebochen061金蟲 (正式寫手)
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Each Eu cation is on the molecular 3-fold axis in a trigonally distorted octahedral coordination field, with one basal triangle being shared with a central [ Eu3(OH)3(OH2)3I4+ cluster and the other with an axial Nb anion. Each Eu atom achieves 8-fold coordination, with one terminal 0 atom, one 0 atom shared by three Eu atoms, two 0 atoms shared by two Eu atoms and one A1 atom, and four atoms of the equatorial [Nb6O19l8- anions, three of which are the p~(Nb2)-0 atoms of one [Nb6019I8- anion while the other is the terminal 0 atom of another [Nb6019I8- anion. |

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每個(gè)銪陽(yáng)離子位于分子三角形扭曲的3重軸的八面體配位區(qū),其中一個(gè)基底三角與中央[Eu3(OH)3(OH2)3I4+配位基團(tuán)共享,其他基底三角與軸向鈮陰離子共享。 每個(gè)銪原子8重配位,一個(gè)終端0原子,一個(gè)0原子由3 銪原子共享,2個(gè)銪原子和一個(gè)Al原子共享兩個(gè)0原子,四個(gè)赤道原子[Nb6O19l8-陰離子,其中3個(gè)為一[Nb6019I8陰離子的p~(Nb2)-0 原子 ,而另一個(gè)是的另一個(gè)[Nb6019I8陰離子的終端0原子。 cluster 配位基團(tuán) 考慮到 (Cluster compounds 配位化合物),但不知翻對(duì)沒(méi)?自己再看看! |

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