somophilic isocyanide insertion什么意思？
有機(jī)合成中，又一篇英文文獻(xiàn)中提到了“somophilic isocyanide insertion”，somophilic什么意思？整句話為“ we succeeded in incorporating
these two building blocks into heteroarenes using visible-lightpromoted somophilic isocyanide insertion”。希望各位大牛指點(diǎn)一二。感激不盡
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somophilic——親單占分子軌道（新生有機(jī)化學(xué)概念）
somophilic isocyanide insertion——親單占分子軌道的異腈插入反應(yīng)
能舉個(gè)例子說明一下它的反應(yīng)機(jī)理嗎？
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.5b02061
Photoredox-Catalyzed Tandem Insertion/Cyclization Reactions of Difluoromethyl and 1,1-Difluoroalkyl Radicals with Biphenyl Isocyanides
Transition Metal-Catalyzed Heterocycle Synthesis Via C-H Activation
作者：Xiao-Feng Wu
p.423, p.425
https://books.google.com.tw/book ... ism&f=false，