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xinlang銅蟲 (初入文壇)
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[求助]
非理想溶液溶解度的測定后,溶解焓應(yīng)該用什么方程求
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非理想溶液溶解度的測定后,溶解焓應(yīng)該用什么方程求 投了一篇JCED,編輯退稿讓重投。 The authors indeed revised their manuscript according to the temperature range and number of solvents. However, in contrast to the guidelines of JCED (http://trc.nist.gov/JournalCoop/ ... ubility%20Data.pdf), they applied the van Hoff equation for calculating thermodynamic properties of solution. This is only valid for ideal solutions and should NOT be applied without accounting for the non-ideality of the systems. This section needs to be revised or should be removed from the paper. 應(yīng)該怎么辦呢?我看了別的文獻好多都是用這方程求得,為什么我的就不行呢? |

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