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kxq19891208金蟲 (正式寫手)
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[求助]
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The former are comprised of infinite networks of metal centers or inorganic clusters bridged by simple organic linkers through metal−ligand coordination bonds. The latter encompass discrete systems in which carefully selected metal centers undergo self-assembly with ligands containing multiple binding sites oriented with specific angularity to generate a finite supramolecular complex. On the most basic level, both SCCs and MOFs share the design of metal nodes linked by organic ligands and such constructs can be broadly defined as metal−organic materials (MOMs). |

金蟲 (正式寫手)

銅蟲 (著名寫手)
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The former are comprised of infinite networks of metal centers or inorganic clusters bridged by simple organic linkers through metal−ligand coordination bonds. The latter encompass discrete systems in which carefully selected metal centers undergo self-assembly with ligands containing multiple binding sites oriented with specific angularity to generate a finite supramolecular complex. On the most basic level, both SCCs and MOFs share the design of metal nodes linked by organic ligands and such constructs can be broadly defined as metal−organic materials (MOMs). 前者是由金屬中心或無機(jī)簇通過簡單的有機(jī)連接體以金屬-配體配位鍵連接起來的無限網(wǎng)絡(luò)(體)。后者則包含著分離的系統(tǒng),在其內(nèi)由精心選出的金屬中心與含有多個(gè)結(jié)合位點(diǎn),位點(diǎn)取特殊角度的配體自我組裝成有限的超分子復(fù)合物。在最基本的水平上,SCCs 和 MOFs兩者都有由有機(jī)配體聯(lián)接起來的金屬節(jié)點(diǎn),這樣的結(jié)構(gòu)(或:含這樣結(jié)構(gòu)的物質(zhì))可粗略地定義為金屬-有機(jī)材料。 |
銅蟲 (著名寫手)
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