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[資源]
EES上剛上線的一篇富鋰綜述
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EES上最新關(guān)于富鋰層狀的綜述 和國內(nèi)集中做納米的文章相比,提出了一些結(jié)構(gòu)上的切入點 感興趣的蟲友可以看看 貼上摘要 The Li-excess oxide compound is one of the most promising positive electrode materials for next generation batteries exhibiting high capacities of >300 mAh g-1 due to the unconventional participation of the oxygen anion redox in the charge compensation mechanism. However, the material synthesis has been proven to be highly sensitive to varying conditions and parameters where nanoscale phase separation may occur that affects the overall battery performance and life. In addition, several thermodynamic and kinetic drawbacks including large first cycle irreversible capacity, poor rate capability, voltage fading, and surface structural transformation need to be addressed in order to reach commercialization. This review will focus on the recent progress and performance trends over the years and provides several guidelines and design considerations based on the library of work done on this particular class of materials. |


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