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醒了要微笑金蟲 (小有名氣)
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請(qǐng)問有誰(shuí)知道四面體的Zn與八面體的Zn在熱力學(xué)穩(wěn)定上有什么區(qū)別啊，文章審稿意見要求我們從這方面進(jìn)行解釋。謝謝大家了，文章投稿問題不斷，請(qǐng)大家多多幫忙。 2) Moreover I doubt that the solubility of the different compounds should be an issue for vapour phase reactions and moreover coordination polymers are not dissolved as persisting periodic entities. Nevertheless, assuming a solvent film on the particles this could affect the product formation, mentioning of Ostwalds step rule would ease the understanding. In addition, I would suggest to compare the energetics of tetrahedral and octahedral zinc carboxylates. Considering the predominantly occuring tetrahedral coordination of zinc in similar compounds might be the reason why reactions only proceed from octahedral to tetrahedral and not vice versa. 老師讓我從這方面進(jìn)行比較 Compare the thermal stability of these tetrahedral and octahedral Zn complexes by the way of energy 在分子動(dòng)力學(xué)方面如何解釋，H2O,DMF,MeOH,在空氣中的濃度問題 Methanol, water and DMF have significantly different volatility: at 25 °C the vapor pressure of methanol is about 127 mmHg, of water is about 24 mmHg, of DMF is about 4 mmHg. This means that there is about 32 times more methanol than DMF available for the VAG process, do the authors have an idea of the possible effects on the kinetics of the reaction? |
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