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yangxing0827銀蟲 (小有名氣)
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[求助]
Reflex利用實驗XRD數(shù)據(jù)確定空間點群和晶格參數(shù),然后搭建COF結構。
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| The supposed structure of COF-LZU1 is analogous to that of COF-54, while each edge of the hexagonal ring was substituted by the framework of (N1E,N4E)-N1,N4-dibenzylidenebenzene-1,4-diamine, the geometry of which was optimized with MS DMol3 module..Firstly, we degraded the symmetry of lattice to P1, inserted the optimised monomer in the empty cell, omitted the redundant carbon atoms and all the hydrogen atoms, and promoted the symmetry to P6/m, outputting the crude structure of COF-LZU1。在文獻中看到這一句話,從Firstly后面沒看懂,這里很明顯是搭建COF的結構的,請教一下是什么意思?具體應該怎么操作。 |

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