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[求助]
大佬們幫忙看看審稿人的這幾條意見(jiàn)是什么意思?
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樓主文章中考察了制備的碳材料上的含氧官能團(tuán)與VOCs之間的相互作用,文章中加了一部分DFT計(jì)算(不同官能團(tuán)與VOCs之間的吸附能),審稿人提出了如下問(wèn)題:1. There is no connection between experimental and theory results. Authors should perhaps compare the experimental FT-IR with the theoretical vibrational frequencies of the modeled surface. 2. Several detailed quantum chemical descriptors are missing. Authors should all the global reactivity descriptors and explain how the energy gap varies with the adsorption of the pollutants. 3. How about the theoretical influence of solvation on the pollutant adsorption and how it is related to the experimental results 4. Because temperature is involved, authors should investigate the thermochemical properties such change in free energy and the enthalpy of formation of the (AC + pollutant) complex 其中第二個(gè)問(wèn)題活性炭也存在能帶energy gap嗎?第三個(gè)問(wèn)題 我的反應(yīng)體系是氣-固態(tài)的存在溶劑化效應(yīng)solvation嗎?第四個(gè)問(wèn)題 enthalpy of formation與兩者之間的吸附能存在什么關(guān)系?有點(diǎn)兒懵 ,希望大佬們幫忙看看這幾個(gè)問(wèn)題怎么解決,在此謝過(guò),不勝感激~ |

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