 |
 |
 |
 |
 |
 |
||
 |
 |
 |
 |
 |
| 查看: 2989 | 回復(fù): 43 | |||
| 當(dāng)前主題已經(jīng)存檔。 | |||
abrastein金蟲 (正式寫手)
|
[交流]
投jpcc被拒，不知還有沒有希望了
|
||
|
一個堅決要拒，一個小修，編輯讓重投。附意見如下，不知道還有沒有希望。 I have received two reviews of your manuscript. One reviewer suggests relatively minor revisions. However, the other reviewer has found that the manuscript does not provide sufficient new physical insight to warrant publication in the Journal of Physical Chemistry. I’m sorry, but based on the serious concerns of this reviewer, I cannot accept your manuscript for publication at this time. However, if you believe that you can adequately address the concerns of this reviewer, then you are welcome to resubmit a revised version of your manuscript at a later date, in which case your manuscript will receive a new submittal date and new manuscript number. Thank you for considering the Journal of Physical Chemistry for the publication of your manuscript. With sincere regards, ------------------------------------ Reviewer(s)' Comments to Author: Reviewer: 1 Recommendation: This paper is not recommended because it does not provide new physical insights. Comments: The referee was interested and also intrigued by the title of this paper which claims Ni UPD on iron. In fact, it sounded rather challenging to observe Ni UPD, i.e. depositing Ni at potential more positive than the standard Nernst potential ENi = -0.5 V/SCE corrected for the solution concentration. In such condition of polaization the Fe electrode is expected to be unstable as it dissolves (EFe = -0.71 V/SCE). Page 2, bottom: arguing that C2 is a UPD process because it is more positive than wave C1 (assigned correctly to bulk Ni deposition) is essentially wrong. A UPD process, as is specified in introduction, refers to a deposition process that occurs at potential positive of the Nernst potential (here – 0.5 V/SCE for Ni). Whatever its origin, peak C2 can, by no mean, be assigned to NI UPD. As far as the reader understands the CV iare starting n Figs. 1-2 from U = - 0.7 V/SCE. At this potential the Ni film is stable but the Fe layer is not stable because one is too close to EFe. Hence Fe slowly dissolves before starting the CV with the Fe/316ss electrode. The observation reported in Fig.1 must therefore be attributed to the re-deposition of dissolved Fe together with Ni deposition. This phenomenon has nothing to do with Ni UPD on Fe. This is rather the opposite that is occurring. As a consequence of this confusion, the purpose of the rest of the paper must be reconsidered. Other comments: - Define acronym PQR. Page 2, § related to QCMB. Conclusion: In conclusion the paper must be rejected. Reviewer: 2 Recommendation: This paper is publishable subject to minor revisions noted. Further review is not needed. Comments: The manuscript is dealing with a very intersting subject, the deposition of a metal and surface alloying on foreign substrates. However I have some remarks before publication seen below. In Fig. 1 and 5, what exact is the meaning of A1? Why is the dissolution charge so low in comparison to deposition? It would be helpful if the current yields are calculated. especially in Fig. 5. Can one assume that the Ni Dissolution is accompanied by passivation or the Ni UPD is accompanied by hydrogen evolution respectively? Would the latter side reaction explain the more than 100 fold charge consumption during deposition in comparison to monolayer formation. Why the presence of Iron ions reduces the Ni UPD as well if one assume an alloy formation? In a couple of cases the alloy deposition should be preferred compared to the single components? [ Last edited by abrastein on 2010-5-16 at 08:31 ] |
回復(fù)此樓» 猜你喜歡
085600，材料與化工321分求調(diào)劑
已經(jīng)有5人回復(fù)
-
求化學(xué)調(diào)劑
已經(jīng)有3人回復(fù)
-
調(diào)劑求院校招收
已經(jīng)有3人回復(fù)
-
材料與化工（0856）304求B區(qū)調(diào)劑
已經(jīng)有8人回復(fù)
-
320分，材料與化工專業(yè)，求調(diào)劑
已經(jīng)有11人回復(fù)
-
0856求調(diào)劑
已經(jīng)有10人回復(fù)
-
266分，求材料冶金能源化工等調(diào)劑
已經(jīng)有9人回復(fù)
-
085600 286分 材料求調(diào)劑
已經(jīng)有8人回復(fù)
-
085701環(huán)境工程，267求調(diào)劑
已經(jīng)有16人回復(fù)
-
286求調(diào)劑
已經(jīng)有12人回復(fù)
smallwww
鐵桿木蟲 (著名寫手)
- 應(yīng)助: 0 (幼兒園)
- 金幣: 6126.2
- 帖子: 1251
- 在線: 26.1小時
- 蟲號: 688514
- 注冊: 2009-01-06
- 性別: GG
- 專業(yè): 機(jī)械動力學(xué)
2樓2010-03-07 09:48:03
smilerobin
至尊木蟲 (文壇精英)
- 應(yīng)助: 87 (初中生)
- 金幣: 24710.3
- 散金: 600
- 紅花: 44
- 帖子: 10734
- 在線: 800.1小時
- 蟲號: 771843
- 注冊: 2009-05-16
- 專業(yè): 自然地理學(xué)
3樓2010-03-07 09:54:12
chemkun
銀蟲 (正式寫手)
- 應(yīng)助: 0 (幼兒園)
- 金幣: 2244
- 散金: 473
- 帖子: 725
- 在線: 287.1小時
- 蟲號: 412732
- 注冊: 2007-06-25
- 性別: GG
- 專業(yè): 功能與智能高分子
4樓2010-03-07 09:55:05
sd71469190
木蟲 (著名寫手)
- 應(yīng)助: 8 (幼兒園)
- 金幣: 3200.1
- 散金: 72
- 紅花: 7
- 帖子: 1030
- 在線: 304.3小時
- 蟲號: 110958
- 注冊: 2005-11-20
- 性別: GG
- 專業(yè): 配位化學(xué)
5樓2010-03-07 09:56:03
ssprodigal
金蟲 (著名寫手)
- 應(yīng)助: 1 (幼兒園)
- 金幣: 1375.5
- 帖子: 1480
- 在線: 62.1小時
- 蟲號: 556634
- 注冊: 2008-05-11
- 性別: GG
- 專業(yè): 果樹學(xué)
6樓2010-03-07 09:58:47
hy861222
木蟲 (職業(yè)作家)
- 應(yīng)助: 12 (小學(xué)生)
- 金幣: 2881.7
- 散金: 2373
- 紅花: 23
- 沙發(fā): 141
- 帖子: 4688
- 在線: 591.4小時
- 蟲號: 810591
- 注冊: 2009-07-17
- 性別: MM
- 專業(yè): 高分子合成化學(xué)
7樓2010-03-07 10:02:50
8樓2010-03-07 10:03:02
weiswallow
鐵桿木蟲 (職業(yè)作家)
- 應(yīng)助: 10 (幼兒園)
- 金幣: 10678.1
- 散金: 4
- 紅花: 4
- 帖子: 3936
- 在線: 738.2小時
- 蟲號: 600115
- 注冊: 2008-09-12
- 專業(yè): 化學(xué)反應(yīng)工程
9樓2010-03-07 10:13:26
zhzimi_2007
木蟲 (職業(yè)作家)
- 應(yīng)助: 0 (幼兒園)
- 金幣: 1759.3
- 散金: 50
- 帖子: 3631
- 在線: 703.6小時
- 蟲號: 450803
- 注冊: 2007-11-04
- 專業(yè): 應(yīng)用數(shù)學(xué)方法
10樓2010-03-07 10:19:58
相關(guān)版塊跳轉(zhuǎn)
我要訂閱樓主 abrastein 的主題更新
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 266分，求材料冶金能源化工等調(diào)劑 +7 | 哇呼哼呼哼 2026-03-27 | 9/450 |
|
|---|---|---|---|---|
|
|
[考研] 085602 307分 求調(diào)劑 +7 | 不知道叫什么！ 2026-03-26 | 7/350 |
|
|
[考研] 289求調(diào)劑 +10 | 新時代材料 2026-03-27 | 10/500 |
|
|
|
[考研] 081200-314 +3 | LILIQQ 2026-03-27 | 4/200 |
|
|
|
[考研] 304求調(diào)劑 +5 | 曼殊2266 2026-03-27 | 5/250 |
|
|
|
[考研] 一志愿中南大學(xué)化學(xué)0703總分337求調(diào)劑 +4 | niko- 2026-03-27 | 4/200 |
|
|
|
[考研] 328求調(diào)劑 +7 | 嗯滴的基本都 2026-03-27 | 7/350 |
|
|
|
[考研] 287求調(diào)劑 +10 | land xuxu 2026-03-26 | 10/500 |
|
|
|
[考研] 安徽大學(xué)專碩生物與醫(yī)藥專業(yè)(086000)324分，英語已過四六級，六級521，求調(diào)劑 +4 | 美味可樂雞翅 2026-03-26 | 4/200 |
|
|
|
[考研] 調(diào)劑 +3 | 李嘉圖·S·路 2026-03-27 | 3/150 |
|
|
|
[考研] 324求調(diào)劑 +5 | hanamiko 2026-03-26 | 5/250 |
|
|
|
[考研]
材料學(xué)碩，求調(diào)劑
 6+5
|
糖葫蘆888ll 2026-03-22 | 10/500 |
|
|
|
[考研] 324求調(diào)劑 +8 | hanamiko 2026-03-26 | 10/500 |
|
|
|
[考研] 333求調(diào)劑 +6 | wfh030413@ 2026-03-23 | 6/300 |
|
|
|
[考研] 081700 調(diào)劑 267分 +11 | 迷人的哈哈 2026-03-23 | 11/550 |
|
|
|
[考研] 263求調(diào)劑 +6 | yqdszhdap－ 2026-03-22 | 10/500 |
|
|
|
[考研] 300分，材料，求調(diào)劑，英一數(shù)二 +5 | 超贊的 2026-03-24 | 5/250 |
|
|
|
[考研] 344求調(diào)劑 +3 | desto 2026-03-24 | 3/150 |
|
|
|
[考研] 384求調(diào)劑 +3 | 子系博 2026-03-22 | 6/300 |
|
|
|
[考研] 275求調(diào)劑 +6 | shansx 2026-03-22 | 8/400 |
|