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小木蟲(金幣+0.5):給個(gè)紅包，謝謝回帖交流
zhangwengui330(金幣+4):謝謝詳細(xì)解說！！ 2010-05-20 14:35:10
A mesoporous material is a material containing pores with diameters between 2 and 50 nm.
Porous materials are classified into several kinds by their size. According to IUPAC notation (see J. Rouquerol et al., Pure & Appl. Chem, 66 (1994) 1739-1758), microporous materials have pore diameters of less than 2 nm and macroporous materials have pore diameters of greater than 50 nm; the mesoporous category thus lies in the middle.have similarly-sized fine mesopores. Mesoporous oxides of niobium, tantalum, titanium, zirconium, cerium and tin have also been reported. According to the IUPAC notation, a mesoporous material can be disordered or ordered in a mesostructure.
The first mesoporous material, with a long range order, was synthesized in the late 80s/ early 90s, by a research group of the former Mobil Oil Company (see Kresge et al., Nature 359 (1992) 710). Since then, research in this field has steadily grown. Notable examples of prospective applications are catalysis, sorption, gas sensing, optics, and photovoltaics.
1.介孔材料的誕生－－1992年MS41系列分子篩(典型的是MCM-41,MCM-48,MCM-50)的合成（嚴(yán)格來講，應(yīng)該是1991年日本人合成出來）：
Nature. 1992, 359, 710-712（J. S. Beck）1y O) J Am Chem Soc. 1992, 114: 10834-10843（J. S. Beck）
Science. 1993, 261: 1299-1303(霍啟升）
2. 介孔材料制備的另一里程碑－－1998年趙東元合成了SBA-15
Science. 1998, 279: 548-552（趙東元）
J. Am. Chem. Soc. 1998, 120, 6024-6036 （趙東元）
3.通過硬模板法合成炭基介孔材料，也是一大重要成績－－1999年由韓國人劉龍完成：
J Am Chem Soc. 2002, 124: 1156-1157( Ryoo R.)
介孔相關(guān)的幾個(gè)牛人的課題組：
http://www.mrl.ucsb.edu/mrl/info/publications/ （G. D. Stucky
http://www.cem.msu.edu/~pinnweb/ （Thomas J. Pinnavaia）
http://www.chem.toronto.edu/staff/GAO/flashed/menu.htm （Ozin's group）
http://homepage.fudan.edu.cn/~dyzhao/ （趙東元） http://rryoo.kaist.ac.kr/pub.html (韓國劉龍 （R. Ryoo）)
http://cheed.nus.edu.sg/~chezxs/Zhao/publication.htm（新加坡趙修松 Xiusong Zhao)
http://www.ucm.es/info/inorg/inv ... iones/2001/2001.htm (西班牙M. Vallet-Regi 首先把介孔材料應(yīng)用到藥物緩釋）
還有幾個(gè)課題組現(xiàn)在沒有了鏈接，但是其課題負(fù)責(zé)人還是記得： 臺灣的牟中原和他的弟子林弘平；上海硅所的施劍林；吉林大學(xué)的肖豐收和裘式倫；大化所的包信和（涉及得不多）
推薦幾篇介孔材料重要的綜述：
Chem. Mater. 1996, 8, 1147-1160 Surfactant Control of Phases in the Synthesis of Mesoporous Silica-Based Materials(Stucky和霍啟升 表面活性劑的堆積參數(shù)和結(jié)構(gòu)的關(guān)系）
Chem. Rev. 1997, 97, 2373-2419 From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis（主要介紹介孔作催化載體的應(yīng)用）
Chem. Rev. 2006, 106, 3790-3812 Advances in the Synthesis and Catalytic Applications of Organosulfonic-Functionalized Mesostructured Materials（有機(jī)官能化介孔的合成及在催化中的應(yīng)用）
Acc. Chem. Res. 2002, 35, 927-935 Structural and Morphological Control of Cationic Surfactant-Templated Mesoporous Silica（牟中原 具體談?wù)摻榭仔蚊驳男纬桑?br />
Angew. Chem. Int. Ed. 2006, 45, 3216–3251 Silica-Based Mesoporous Organic-Inorganic Hybrid Materials（Frank Hoffmann 所著，非常好）
Acc.Chem.Res.2005, 38,305-312 Past, Present, and Future of Periodic Mesoporous Organosilicas-The PMOs（O'zin 重點(diǎn)介紹周期性介孔）
NATURE 2002 417 813 Ordered porous materials for emergeing application
（大牛Davis所著）Chem. Mater. 1999, 11, 2633-2656 Tailored Porous Materials(Thomas J.)
介孔分子篩的應(yīng)用
介孔分子篩吸附氨基酸：
Carbon 44 (2006) 530–536 Adsorption of L-histidine over mesoporous carbon molecular sieves(印度人 A. Vinu）
Separation and Purification Technology 48 (2006) 197–201 Amino acid adsorption onto mesoporous silica molecular sieves （首篇）
介孔分子篩吸附蛋白質(zhì)（酶）
Journal of Molecular Catalysis B－ Enzymatic 2（1996） 115－ 126 Enzyme immobilization in MCM-4 1 molecular sieve（首篇）
J. Am. Chem. Soc. 1999, 121, 9897-9898 Mesoporous Silicate Sequestration and Release of Proteins（stucky)
J. AM. CHEM. SOC. 2004, 126, 12224-12225 Protein Encapsulation in Mesoporous Silicate-The Effects of Confinement on Protein Stability, Hydration, and Volumetric Properties
J. Phys. Chem. B 2003, 107, 8297-8299 Adsorption of Cytochrome C on New Mesoporous Carbon Molecular Sieves(Vinu, A)
介孔分子篩負(fù)載催化劑
J. Phys. Chem. B 2006, 110, 15212-15217 Fabrication and characterization of mesoporous Co3O4 core-mesoporous silica shell nanocomposites（典型的core－shell結(jié)構(gòu)）
CHEM. COMMUN., 2003, 1522–1523 Ultra-thin porous silica coated silver–platinum alloy nano-particle as a new catalyst precursor)
Applied Catalysis A General 308 (2006) 19–30 Carbon oxide hydrogenation over silica-supported iron-based catalysts Influence of the preparation route%m;
Chem. Commun., 2005, 348–350 Metallic Ni nanoparticles confined in hexagonally ordered mesoporous silica material)
介孔分子篩在藥物可控釋放方面的應(yīng)用
Chem. Mater. 2001, 13, 308-311 A New Property of MCM-41, Drug Delivery System（Vallet-Regi 首篇）
Nature 2003, 421, 350 – 353 Photocontrolled reversible release of guest molecules from coumarinmodified modified mesoporous silica（第一次只能化）
J. AM. CHEM. SOC. 2005, 127, 8916-8917 Fabrication of Uniform Magnetic Nanocomposite Spheres with a Magnetic Core-Mesoporous Silica Shell Structure-support（施劍林 所謂的“藥物分子運(yùn)輸車”）
Angew. Chem. Int. Ed. 2005, 44, 5038 –5044 Stimuli-Responsive Controlled-Release Delivery System Based on Mesoporous Silica Nanorods Capped with Magnetic Nanoparticles（Victor S.-Y. Lin* 在智能介孔藥物釋放方面是貢獻(xiàn)巨大）介孔分子篩吸附廢水陽離子
Chemosphere 59 (2005) 779–786 Heavy metals removal from electroplating wastewater by aminopropyl-Si
Environ. Sci. Technol.2000, 34,4822-4827 Surfactant-Templated Mesoporous Silicate Materials as Sorbents for Organic Pollutants in Water
Ind. Eng. Chem. Res. 2004, 43, 1478-1484 Highly Selective Adsorption of Pt2+ and Pd2+ Using Thiol-Functionalized Mesoporous Silica
介孔分子篩在色譜中的應(yīng)用
Chem. Commun., 2002, 752 - 753 Biomolecule separation using large pore mesoporous SBA-15 as a substrate in high performance liquid chromatography
Electrophoresis 2006,27,742–748 Large-pore mesoporous SBA-15 silica particles with submicrometer size as stationary phases for high-speed CEC seperation
介孔分子篩作為硬模板
Adv. Mater. 2001, 13, 677-681 Ordered Mesoporous Carbons（Ryong Ryoo）
Microporous and Mesoporous Materials 63 (2003) 1–9 Synthesis and characterization of spherical carbon and polymer capsules with hollow macroporous core and mesoporous shell structures
介孔分子篩復(fù)合材料（實(shí)現(xiàn)光學(xué)性能，比如摻入二氧化鈦，量子點(diǎn)）
J. Phys. Chem. B 2005, 109, 12309-12315 Synthesis and Characterization of Nano titania Particles Embedded in Mesoporous Silica with Both High Photocatalytic Activity and Adsorption Capability
Chem. Mater. 2005, 17, 1269-1271 Preparation of Mesoporous Titania Thin Films with Remarkably High Thermal Stability
J. AM. CHEM. SOC. 2006, 128, 688-689 Magnetic Fluorescent Delivery Vehicle Using Uniform Mesoporous Silica Spheres Embedded with Monodisperse Magnetic and Semiconductor Nanocrystals
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