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photochemical displacement of benzene from M(II) complexes (M =Fe, Ru, Os).應(yīng)該怎么翻譯 |
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見文獻：Photochemical displacement of the benzene ligand in [(η6-C6H6)Ru(CH3CN)2(L)]2+ and [(η6-C6H6)Ru(CH3CN)(L2)]2+ (L=CH3CN, PPh3, L2=dppe, bipy) ，Inorganica Chimica Acta，Volume 357, Issue 9, 5 July 2004, Pages 2721-2727。 Wolfgang Lacknera, Christina Maria Standfest-Hausera, Kurt Mereiterb, Roland Schmida and Karl Kirchnera, , aInstitute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria bInstitute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria Received 10 February 2004; accepted 28 February 2004. Available online 9 April 2004. Abstract Photoirradiation with a 150 W medium-pressure Hg lamp for 17 h in acetontrile as the solvent replaces the benzene ligand in the cationic complexes [(η6-C6H6)Ru(CH3CN)2(L)]2+ and [(η6-C6H6)Ru(CH3CN)(L2)]2+ (L=CH3CN, PPh3, L2=dppe, bipy) with acetonitrile. These replacements are equally clean to those reported before for analogous CpRu+ complexes. Crystal structures of the products obtained are included. Photoirradiation with a 150 W medium-pressure Hg lamp for 17 h in acetontrile as the solvent replaces the benzene ligand in the cationic complexes [(η6-C6H6)Ru(CH3CN)2(L)]2+ and [(η6-C6H6)Ru(CH3CN)(L2)]2+ (L=CH3CN, PPh3, L2=dppe, bipy) with acetonitrile. These replacements are equally clean to those reported before for analogous CpRu+ complexes. |
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