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563324898木蟲 (知名作家)
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| 電流強度隨酶的引入進一步顯著減小，這主要是因為酶對成核過程的影響。聚合物膜的整體成長被抑制由于酶 分子摻入膜。導(dǎo)致該膜的電導(dǎo)率的下降。這可能被解釋為物理摻入的酶分子阻礙了膜的空間生長，因為酶巨大的分子量（140 kD）。另一原因可能是酶附著在鉑電極表面，這可能導(dǎo)致EDOT聚合弱的電化學(xué)行為。因為AO阻礙了EDOT快速擴散到電極表面并連續(xù)形成EDOT+●.低的EDOT濃度或高的AO濃度導(dǎo)致電化學(xué)聚合過程延遲或被抑制，甚至該復(fù)合膜不能被獲得。 |
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wypward(金幣+1):歡迎新蟲，謝謝參與 2010-06-07 18:44:54
563324898(金幣+10, 翻譯EPI+1): 2010-06-07 21:09:48
wypward(金幣+1):歡迎新蟲，謝謝參與 2010-06-07 18:44:54
563324898(金幣+10, 翻譯EPI+1): 2010-06-07 21:09:48
With the introduction of enzymes ，the degree of current had significantly fell dawn because of the influence of enzymes in nucleation process. In this nucleation process,the growth of polymer membranes was restained result of the adding of enzyme molecular ,then ,the decline of conductivity was in the follow way .The reasons may be rely on the molecular weight of enzyme. It is so big that hampered the growth of polymer membranes. Another reason may be the attachment of enzymes to the platinum electrode surface, which may lead EDOT polymerization process to gain weak electrochemical behavior. Because AO hindered the rapid spreading EDOT to the electrode surface ,which continue form EDOT+●. Another reason maybe the high concentration of AO leading the electrochemical polymerization process in delay or suppressed, even this composite membrane cannot be obtained. |
2樓2010-06-07 17:57:04
fengqiu3160
金蟲 (正式寫手)
- 應(yīng)助: 0 (幼兒園)
- 金幣: 1915.4
- 散金: 9
- 帖子: 445
- 在線: 67.3小時
- 蟲號: 1006985
- 注冊: 2010-04-27
- 專業(yè): 電化學(xué)
563324898(金幣+10): 2010-06-07 21:10:21
| Current intensity further decreases significantly with the introduction of enzyme , and this mainly becauses of the effects of enzyme on the nucleation process.overall growth of polymer membranes isi nhibited and this becauses the enzyme doping into the membranes,leading to a decline in the conductivity of membranes.Because the molecules weight of enzyme is large(140KD),this can be interpreted as the physical incorporation of the enzyme molecules hindering the growth of the membrane space.The other reason may be the enzyme attaches to the platinum electrode surface, leading to the electrochemical behaviror of EDOT's weak polymerization. Because the AO stopes the EDOT to quickly diffuse to the electrod surface and the EDOT is successively changed into EDOT+●,the low concentration of EDOT or the high concentration of AO lead to the inhibition or delay of electrochemical polyerization process,or even the composite film can not be obtained. |
3樓2010-06-07 18:18:33
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