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層內(nèi)脫水時(shí),納米管受軸向力,管形貌能夠保持穩(wěn)定,層間脫水時(shí)納米管受徑向力,因而會(huì)塌陷斷裂。 與層間脫水形成Ti-O鍵同步,在納米管內(nèi)硝酸鎳分解,集聚形成Ni0顆粒,當(dāng)其直徑達(dá)到與納米管內(nèi)徑接近時(shí),就會(huì)產(chǎn)生一個(gè)支撐力,抵消擠壓的應(yīng)力,避免塌陷發(fā)生 , [ Last edited by wolfmanhd on 2010-7-5 at 15:09 ] |
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When dehydration occured in layers, the nanotubes was under axial force, the tube shape can remain stable.When dehydration occured between layers, the nanotubes was under radial force, thus they will collapse to fracture. Ni(N03)3 decomposed in the nanotubes when Ti-O bond was formed in dehydration between layers, then NiO was formed by accumulation. If the diameter of NiO increased closely to that of the nanotubes, it will bring about a support force to offset compression stress so as to avoid the collapse. |
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