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hejin04c榮譽(yù)版主 (著名寫(xiě)手)
小木蟲(chóng)樂(lè)樂(lè)蟲(chóng)
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[交流]
【求助】審稿意見(jiàn)大家?guī)兔纯矗毖剑? 已有6人參與
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| Section 3.4 is missing some good points: I'm a bit surprised to see thin-layer behaviour (Ip proportional to scan rate) at such high scan rates. The authors just reported Ip vs scan rate from 100 mV s-1 to 1V s-1. I would like to see some CVs at very low scan rate, I would say from 5 mV-1 to 100 mV s-1 to see the dependence of the Ip with the scan rate. By eye, based on the data reported in figure 4, the peak separation seems to me higher than 59mV, so the authors should explain this. |

金蟲(chóng) (小有名氣)
榮譽(yù)版主 (著名寫(xiě)手)
小木蟲(chóng)樂(lè)樂(lè)蟲(chóng)

金蟲(chóng) (正式寫(xiě)手)
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Section 3.4 is missing some good points: I'm a bit surprised to see thin-layer behaviour (Ip proportional to scan rate) at such high scan rates. The authors just reported Ip vs scan rate from 100 mV s-1 to 1V s-1. I would like to see some CVs at very low scan rate, I would say from 5 mV-1 to 100 mV s-1 to see the dependence of the Ip with the scan rate. By eye, based on the data reported in figure 4, the peak separation seems to me higher than 59mV, so the authors should explain this 本文來(lái)自: 小木蟲(chóng)論壇 http://www.gaoyang168.com/bbs/viewthread.php?tid=2275929&fpage=2 好像是他讓你在低掃描速度再把實(shí)驗(yàn)重新做一下,他想看看在5 mV-1 to 100 mV s-1 的情況,另外他說(shuō)圖四峰距超過(guò)59mv,希望你解釋一下,不是你的領(lǐng)域,不知說(shuō)的對(duì)不 |
金蟲(chóng) (小有名氣)
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其實(shí)就是看看你的體系的可逆性如何,然后才能判斷Ip和scan rate的關(guān)系,對(duì)于可逆,半可逆,不可逆體系,這個(gè)關(guān)系是不同的 因此他要看你在更小的電流下的結(jié)果,采用大的掃描速度,結(jié)果是不可靠的。 因?yàn)閽呙杷俣冗^(guò)大,往往造成峰寬化,反而導(dǎo)致Ip值減小,所以就不太符合規(guī)律。 你要給出的結(jié)果,應(yīng)該按照審稿人的建議補(bǔ)實(shí)驗(yàn)。 只是個(gè)人根據(jù)文意的猜測(cè),具體情況具體分析,不知道你要討論的是什么體系。 |
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