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【求助】有什么資料或書(shū)或文章可參考?
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用MOLPRO計(jì)算時(shí),什么叫活性空間?占距軌道,凍芯軌道? 有什么資料或書(shū)或文章可參考啊? For the AsP (X1Σ+) molecule, the calculations are carried out in C2v symmetry with the order of the irreducible representations as a1/b1/b2/a2. Eight MOs are put into active space, including four a1, two b1, two b2, which correspond to the 4s4p shells of the As atom and 3s3p shells of the P atom. The rest of the electrons are put into the closed-shell orbits, that to say, ten a1, four b1, four b2, one a2. 什么意思?特別是第2段? 跪請(qǐng)高人指教 |
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