| 2 | 1/1 | 返回列表 |
| 查看: 486 | 回復(fù): 1 | |||
crx0510金蟲 (小有名氣)
|
[交流]
【求助】投了篇晶體學(xué)報,審稿給提了幾個問題,不知道怎么回答,在此請教一下高手
|
|
1. This compound crystallizes in a chiral space group but no Flack parameter has been reported 2. In the cif file: _diffrn_measured_fraction_theta_max 0.964 _diffrn_reflns_theta_full 25.00 Some explanation should be made as to why the measured coverage is less that 0.97. 3. The fcf report indicates that 83 reflections were omitted between theta(min) to theta(max). Some explanation should be provided as to why there reflections were omitted. 5. For 5-coordinate complexes the tau-parameter has been used to indicate where the coordination geometry lies on the continuum between square pyramidal (C4v) and trigonal bipyramidal (D3h). The reference is: Addison, A. W., Rao, T. N., Reedijk, J., van Rijn, J. & Verschoor, G. C. (1984). J. Chem. Soc. Dalton Trans. pp. 1349-1356. The calculated values should included in the Abstract as well. |
木蟲 (職業(yè)作家)
|
1:手性結(jié)構(gòu),解釋一下為何沒作絕對構(gòu)型, 用的是Mo靶,無法判定絕對構(gòu)型 2:完整度低, 可能晶體小,數(shù)據(jù)質(zhì)量問題,衍射能力問題,晶體結(jié)構(gòu)無序等等。 3:結(jié)構(gòu)靜修中為何忽略了83個衍射點,需要解釋 可能Fc與Fo差的比較多,從晶體結(jié)構(gòu)中找原因 5:文獻問題 自己看吧,解釋一下。 樓主的結(jié)構(gòu)不是自己解的吧。 |

| 2 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 277材料科學(xué)與工程080500求調(diào)劑 +7 | 自由煎餅果子 2026-03-16 | 7/350 |
|
|---|---|---|---|---|
|
[考研] 求調(diào)劑一志愿海大,0703化學(xué)學(xué)碩304分,有大創(chuàng)項目,四級已過 +6 | 幸運哩哩 2026-03-22 | 10/500 |
|
|
[考研] 287求調(diào)劑 +8 | 晨昏線與星海 2026-03-19 | 9/450 |
|
|
[考研] 一志愿中南化學(xué)(0703)總分337求調(diào)劑 +9 | niko- 2026-03-19 | 10/500 |
|
|
[考研] 291 求調(diào)劑 +3 | 化工2026屆畢業(yè)?/a> 2026-03-21 | 3/150 |
|
|
[考研] 354求調(diào)劑 +7 | Tyoumou 2026-03-18 | 10/500 |
|
|
[考研] 384求調(diào)劑 +3 | 子系博 2026-03-22 | 4/200 |
|
|
[考研] 初試 317 +7 | 半拉月丙 2026-03-20 | 7/350 |
|
|
[考研] 333求調(diào)劑 +5 | 87639 2026-03-21 | 7/350 |
|
|
[考研] 求調(diào)劑 +3 | 13341 2026-03-20 | 3/150 |
|
|
[考研] 求助 +5 | 夢里的無言 2026-03-21 | 6/300 |
|
|
[考研] 266求調(diào)劑 +3 | 哇呼哼呼哼 2026-03-20 | 3/150 |
|
|
[考研] 330求調(diào)劑0854 +3 | assdll 2026-03-21 | 3/150 |
|
|
[考研] 085601調(diào)劑 358分 +3 | zzzzggh 2026-03-20 | 4/200 |
|
|
[考研] 265求調(diào)劑 +3 | Jack?k?y 2026-03-17 | 3/150 |
|
|
[考研] 303求調(diào)劑 +5 | 睿08 2026-03-17 | 7/350 |
|
|
[考研] 304求調(diào)劑 +7 | 司空. 2026-03-18 | 7/350 |
|
|
[考研] 一志愿武漢理工材料工程專碩調(diào)劑 +9 | Doleres 2026-03-19 | 9/450 |
|
|
[考研] 一志愿西安交通大學(xué) 學(xué)碩 354求調(diào)劑211或者雙一流 +3 | 我想要讀研究生 2026-03-20 | 3/150 |
|
|
[考研] 286求調(diào)劑 +6 | lemonzzn 2026-03-16 | 10/500 |
|