| 6 | 1/1 | 返回列表 |
| 查看: 1075 | 回復(fù): 5 | |||
7zzz銅蟲 (小有名氣)
|
[交流]
【求助】Catalytic Water Oxidation是什么意思? 已有3人參與
|
|
催化水氧化?? 說的是什么啊 文章的結(jié)論一點(diǎn)都沒看懂,有么有行家指點(diǎn)一下。先謝過 This study provides evidence that catalytic water oxidation driven by CAN provides access to reaction pathways that diverge from the prevailing “acid base” mechanism for single-site catalysts. The preference for each of these pathways is dependent on reaction conditions and electron density at the metal site. The position of the RDS is shown to be sensitive to electron density at the Ru center and shows that higher catalytic activity is attained when the [RuV OO]2 is made accessible(i.e., RDS is kO2′ rather than kO2). However, too much density at the metal site can compromise the critical bond formation step, thus highlighting the inherent limitation for achieving high catalytic rates with catalysts of this type. This study also demonstrates that a minor auxiliary reaction pathway may be operative that enables the incorporation of an O-atom from a source other than water (e.g., CAN) into the dioxygen product. These findings provide important insight into the design and study of homogeneous water oxidation catalysts. |
鐵桿木蟲 (著名寫手)
銅蟲 (小有名氣)
木蟲 (著名寫手)
銅蟲 (小有名氣)
木蟲 (著名寫手)
| 6 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 311求調(diào)劑 +6 | 26研0 2026-03-15 | 6/300 |
|
|---|---|---|---|---|
|
[考研] 297求調(diào)劑 +8 | 戲精丹丹丹 2026-03-17 | 8/400 |
|
|
[考研] 302求調(diào)劑 +10 | 呼呼呼。。。。 2026-03-17 | 10/500 |
|
|
[考研] 280求調(diào)劑 +6 | 咕嚕曉曉 2026-03-18 | 7/350 |
|
|
[考研] 生物學(xué)071000 329分求調(diào)劑 +3 | 我愛生物生物愛?/a> 2026-03-17 | 3/150 |
|
|
[考研] 334求調(diào)劑 +3 | 志存高遠(yuǎn)意在機(jī)?/a> 2026-03-16 | 3/150 |
|
|
[考研] 材料與化工求調(diào)劑 +6 | 為學(xué)666 2026-03-16 | 6/300 |
|
|
[考研] 277調(diào)劑 +5 | 自由煎餅果子 2026-03-16 | 6/300 |
|
|
[考研] 材料工程專碩調(diào)劑 +5 | 204818@lcx 2026-03-17 | 5/250 |
|
|
[考研] 考研化學(xué)學(xué)碩調(diào)劑,一志愿985 +4 | 張vvvv 2026-03-15 | 6/300 |
|
|
[考研] 【0856】化學(xué)工程(085602)313 分,本科學(xué)科評(píng)估A類院;瘜W(xué)工程與工藝,誠求調(diào)劑 +7 | 小劉快快上岸 2026-03-11 | 8/400 |
|
|
[考研] 求調(diào)劑,總分315,考的生物醫(yī)藥,一志愿湖南師范大學(xué)。調(diào)劑到任何專業(yè)都可以 +4 | 小丁想進(jìn)步 2026-03-11 | 5/250 |
|
|
[考研] 機(jī)械專碩325,尋找調(diào)劑院校 +3 | y9999 2026-03-15 | 5/250 |
|
|
[考研] 085600調(diào)劑 +5 | 漾漾123sun 2026-03-12 | 6/300 |
|
|
[考研] 297求調(diào)劑 +4 | 學(xué)海漂泊 2026-03-13 | 4/200 |
|
|
[考研] 材料與化工(0856)304求B區(qū)調(diào)劑 +6 | 邱gl 2026-03-12 | 7/350 |
|
|
[考研] 304求調(diào)劑 +7 | 7712b 2026-03-13 | 7/350 |
|
|
[考研] 求調(diào)劑 +5 | 一定有學(xué)上- 2026-03-12 | 5/250 |
|
|
[考研] 0703化學(xué)求調(diào)劑 +7 | 綠豆芹菜湯 2026-03-12 | 7/350 |
|
|
[考博] 福州大學(xué)楊黃浩課題組招收2026年專業(yè)學(xué)位博士研究生,2026.03.20截止 +3 | Xiangyu_ou 2026-03-12 | 3/150 |
|