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分別在MgCl2和NaCl稀溶液中,用AFM研究了四方相ZrO2納米涂層的表面排斥力隨作用距離的變化關系。當作用距離較遠時,表現為長程排斥力,當作用距離較近時,為強烈的短程排斥力。Mg2+在ZrO2納米涂層表面具有特征吸附,而Na+卻沒有發(fā)生特征吸附,表現出惰性電解質的特征。可以排除Cl-的特征吸附的可能性。隨著MgCl2濃度的增大,滲透通量呈明顯下降的趨勢。隨著NaCl濃度的增大,滲透通量呈稍有增大的趨勢。膜的表面態(tài)(結構)與不同結構的水分子的相互作用是決定滲透通量的主要內在因素。 致謝:衷心感謝作者的導師蔡啟瑞老師(中科院資深院士)曾給予的指導。 |
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MgCl2 and NaCl respectively in dilute solution, with AFM research the tetragonal phase coating surface ZrO2 nano repelling force with the changing relations between the effective distance. When the effect distance is farther, performance for long-range repelling force, when the effect distance is close, for strong short-range repelling force. Mg2 + ZrO2 nano coating surface has the characteristics of adsorption, while making + did not produce feature adsorption, show inert solid electrolyte characteristics. Can eliminate Cl - features adsorption of possibilities. Along with the increase of MgCl2 concentration, permeate flux show clear downward trend. Along with the increase of concentration NaCl, permeate flux is slightly increasing trend. Membrane surface state (structure) and different structure of water molecules interactions are decided the main internal factors of infiltration flux. Acknowledgement: thank the authors mentor CaiQiRui teacher of Senior academician of Chinese academy of sciences |
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