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| All these studies suggest that W-based photocatalysts, although few studied, would be the promising group of catalysts worthy of further in-depth study. It should be noted that all the W-based catalysts mentioned above are oxide and most of them only showed activity under UV light or only had the activity for oxygen evolution under visible light due to their unfavorable band gap or band position. On the other hand, several multi-component sulfides have recently been reported to show high photocatalytic efficiency, suggesting that such sulfides could be a new class of efficient visible-light-driven photocatalysts. |
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All these studies suggest that W-based photocatalysts, although few studied, would be the promising group of catalysts worthy of further in-depth study. It should be noted that all the W-based catalysts mentioned above are oxide and most of them only showed activity under UV light or only had the activity for oxygen evolution under visible light due to their unfavorable band gap or band position. On the other hand, several multi-component sulfides have recently been reported to show high photocatalytic efficiency, suggesting that such sulfides could be a new class of efficient visible-light-driven photocatalysts. 所有這些研究都表明,鎢基光催化劑會(huì)雖然很少被關(guān)注,但確實(shí)是一類很有前景、值得進(jìn)一步研究的催化劑。應(yīng)該指出的是,前文提到的鎢基催化劑均為氧化物,由于這類催化劑的帶隙或者能帶位置所限,它們中的大部分只在紫外光下才具有活性,或者在可見(jiàn)光下只有析氧活性。另一方面,最近有許多報(bào)道稱多組分硫化物表現(xiàn)出高的光催化效率,表明這些硫化物可能是一類有效的可見(jiàn)光驅(qū)動(dòng)的光催化劑。 |
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