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【答案】應(yīng)助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ... ypfkb(金幣+5, 翻譯EPI+1): 2011-04-14 09:24:25 ringzhu(金幣+50): ~~ 2011-04-18 18:52:28 ringzhu(金幣+50): ~~ 2011-04-18 18:53:01 ringzhu(金幣+5): ~~ 2011-04-18 18:53:08
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By verification of different dynamics models to have a conclude that the control step of catalytical dehydrogenation of NO on Cu/ZSM-5 is surface bimolecular reaction happened between two adsorbed NO moleculars, but also the sorption of NO on active sites is reversible and the decomposition reaction order for NO is 2,for O is negative number,respectively. Enriched Oxygen repress the decomposition reaction. Measuring the reaction activation energy is E=52kJ.mol-1 and the relationship between rate constant and temperuture T based on this dynamics models. |
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