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寶MMC金蟲 (小有名氣)
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[求助]
求助翻譯一段化學英文文獻，謝謝
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| The combination of reaction and distillation in one reactive distillation (RD) unit can lead to significant reduction of investment and operational cost. However, interactions between reactions and separation increase complexity and require a better understanding of the process. Whereas RD is intensively studied for years, only few works have been published on vapour–liquid–liquid (VLL) systems, thus our investigations focus on VLL reactive systems. Experimental investigations have already been published for the production of butyl acetate (Steinigeweg and Gmehling, 2002) or amyl acetate (Chiang et al., 2002) but, to the best of our knowledge, none for n-propyl acetate reactive distillation; thus, information about n-propyl acetate synthesis can hardly be found in literature. Investigations on reactive membrane separation have led Huang et al. (2005) to publish data on chemical equilibrium. Bart et al. (1996) have published a kinetic modelling of the n-propyl acetate synthesis catalysed by an ion exchange resin (Dowex) as well as Steinigeweg (2003) with the Amberlyst-15. Unfortunately, uncertainty remains on the chemical equilibrium constant value. Finally, no data about reactive distillation pilot-plant experiments is published. |
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溫艷玲寒香
金蟲 (正式寫手)
- 翻譯EPI: 1
- 應助: 0 (幼兒園)
- 金幣: 1094.5
- 散金: 26
- 紅花: 3
- 帖子: 362
- 在線: 82.1小時
- 蟲號: 889570
- 注冊: 2009-10-31
- 性別: MM
- 專業(yè): 色譜分析
【答案】應助回帖
寶MMC(金幣+20, 翻譯EPI+1): 謝謝 2011-05-23 14:04:30
在一個反應蒸餾(RD)單元里，將反應與精餾相結合,可以有效降低投資和運營成本。然而,反應和分離之間的相互作用增加了反應復雜性而且要求有更好的理解的過程。而對于反應蒸餾(RD)單元的研究已進行了許多年,但只有少數(shù)的作品發(fā)表在vapour-liquid-liquid(VLL)系統(tǒng),因此使我們的研究集中在VLL反應系統(tǒng)中。對于生產(chǎn)醋酸丁酯(Steinigeweg和Gmehling,2002)或醋酸戊酯(2002年)的實驗研究已經(jīng)公布，但是,據(jù)我們所知,沒有對乙酸正丙酯進行反應蒸餾;因此,很難查到有關合成醋酸正丙酯的文獻�？疾斓幕A上,黃2005在化學平衡上公布無功膜分離的有關數(shù)據(jù)。巴特1996已經(jīng)出版了動力學建模的一種離子交換樹脂(Dowex)的有關信息，同樣Steinigeweg在2003用Amberlyst-15促合成乙酸正丙酯。不幸的是,不確定性仍然是化學平衡常數(shù)的價值。最后,還沒有對有關反應蒸餾實際生產(chǎn)規(guī)模試驗的數(shù)據(jù)發(fā)表。 |
2樓2011-05-23 11:11:25
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