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[求助]
草酸鎳 cif文件
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草酸鎳 cif文件: Card Information Names: alpha-Nickel Oxalate Hydrate Formula: C2 Ni O4 !2 H2 O PDF Number: 25-581 Quality: indexed Subfiles: inorganic organic COR Cell and Symmetry Information System: monoclinic Space Group: C2/c (no. 15) a: 11.775 b: 5.333 c: 9.833 b: 127.2 Density (Dx): 2.468 Z: 4 Instrument Information Radiation: Fe Wavelength: 1.93604 Instrument(d): unknown Instrument(I): diffractometer I type: unknown Comments and Additional Information Powder: Also used CoKa = 1.7902. Literature References General: Deyrieux et al. Bull. Soc. Chim. Fr. 25 (1973) Unit Cell: Ibid. Bull. Soc. Chim. Fr. ( ) Peak Data PeakList h k l d I -2 0 2 4.7200 100 0 0 2 3.9200 15 -1 1 2 3.5700 13 -3 1 2 3.1000 1 -4 0 2 2.9420 45 -3 1 3 2.7100 1 0 2 0 2.6650 4 -1 1 3 2.6370 13 0 2 1 2.5280 14 -2 0 4 2.3930 3 -2 2 2 2.3220 2 -3 1 4 2.2330 15 -5 1 3 2.1360 4 -2 2 3 2.0670 15 -1 1 4 2.0350 9 -4 2 2 1.9750 4 0 0 4 1.9590 2 -6 0 4 1.9050 30 0 2 3 1.8660 13 -3 1 5 1.8330 2 -2 2 4 1.7810 20 -1 3 2 1.6680 2 -1 1 5 1.6410 4 -3 3 2 1.6110 2 -4 2 5 1.5800 12 4 2 1 1.5710 4 3 3 0 1.5440 3 -7 1 5 1.5360 8 -8 0 4 1.4740 10 |
鐵桿木蟲 (職業(yè)作家)
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*data for ICSD #150590 Coll Code 150590 Rec Date 2006/04/01 Mod Date 2008/02/01 Chem Name Nickel Oxalate Dihydrate - Alpha Structured Ni (C2 O4) (H2 O)2 Sum C2 H4 Ni1 O6 ANX AB2X6 D(calc) 2.47 Title Contribution a l'etude des oxalates de certains metaux bivalents. III. Structure cristalline des oxalates dihydrates de manganese, de cobalt, de nickel et de zinc. Polymorphisme des oxalates dihydrates de cobalt et de nickel Author(s) Deyrieux, R.;Berro, C.;Peneloux, A. Reference Bulletin de la Societe Chimique de France (Vol=Year) (1973), 1973(1), 25-34 Golden Book of Phase Transitions, Wroclaw (2002), 1, 1-123 Unit Cell 11.7748(77) 5.3328(9) 9.8326(64) 90. 127.21(4) 90. Vol 491.72 Z 4 Space Group C 1 2/c 1 SG Number 15 Cryst Sys monoclinic Pearson mS52 Wyckoff f4 e Red Cell C 5.332 6.463 8.272 81.984 71.196 65.634 245.862 Trans Red 0.000 1.000 0.000 / 0.500 0.500 0.000 / -0.500 0.500 -1.000 Comments A HT-form exists in Cccm (2nd ref., Tomaszewski) Cell in I12/c1-setting: a'=9.762, beta'=106.13 The structure has been assigned a PDF number (calculated powder diffraction data): 01-073-2580 Structure type : FeC2O4 X-ray diffraction from single crystal No R value given in the paper. At least one temperature factor missing in the paper. Atom # OX SITE x y z SOF H Ni 1 +2 4 e 0. 0.175 0.250 1. 0 C 1 +3 8 f 0.037 0.674 0.335 1. 0 O 1 -2 8 f 0.085 0.471 0.420 1. 0 O 2 -2 8 f 0.085 0.877 0.420 1. 0 O 3 -2 8 f 0.172 0.174 0.250 1. H2 *end for ICSD #150590 |
鐵桿木蟲 (職業(yè)作家)
木蟲 (初入文壇)
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