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煙云聽雨鐵桿木蟲 (正式寫手)
金蟲
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[求助]
求翻譯一段英文文獻(有機化學)
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Construction of a Follow-Up Library and Binding Studies. The observation that the majority of potent binding compounds possessed basic nitrogen prompted us to consider the construction of unique analogues containing alternative basic nitrogen heterocycles.the ideal method would furnish the heterocyclic products diastereoselectively with a minimum of manipulations and allow for independent functionalization at both the left- and righthand hemispheres on the core scaffold. During the scale-up of Stemona scaffolds for library synthesis, we noted that the tandem Diels–Alder/Schmidt reaction could be halted at the Diels–Alder stage and the azido diketone product isolated by judicious choice of Lewis acid and by limiting the number of equivalents added. |
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至尊木蟲 (職業(yè)作家)
- 翻譯EPI: 509
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2樓2011-07-20 08:39:03
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3樓2011-07-24 20:45:33
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