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cmj_1237銀蟲 (初入文壇)
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[求助]
求晶體精修,本人菜鳥中的菜鳥
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本人對晶體不懂,投稿后,編輯回復(fù)如下,希望高手能幫解答,不勝感謝。請留下郵箱,把相關(guān)數(shù)據(jù)發(fā)至您郵箱,主要是下列的2、5、6條。(2條的問題直接在cif文件中刪除行么?是不是需要在精修的過程中用到相關(guān)的軟件,實在不懂。 1. In the abstract and in the comments, you mention N-H...O H-bonds. There are no oxygen atoms in your structure. Please correct. 2. The C-H...Br contacts are too long to qualify for H-bonds. Please remove from the text and the tables. 3. Please mention about restrictions on thermal parameters for H atoms of the amino group. 4. I would suggest to mention the intra-molecular H bond in the Abstract. Its formation is very important for physical properties of crystals of this class of compound (did you check these crystals for thermochromism?) 5. Also, formation of stacks along y axis is worth mentioning. 6. If it is allowed by the quality of the experiment, please refine the amino hydrogens without geometric restrictions. For such prototropic tautomeric systems, the objective positions of the hydrogens are of importance. |
找到一些相關(guān)的精華帖子,希望有用哦~
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