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jjxiang捐助貴賓 (著名寫手)
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[求助]
翻譯一段英文文獻(xiàn)·····
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MAF synthesis is relatively insensitive to the reaction condi- tions because most of the common species presented in the solution, such as anions and solvent molecules, can hardly compete with the targeted metal azolate bonds, which is parti- cularly true for those composed of soft metal ions and diazolates. Nevertheless, the coordination affinity varies among different species, including different azolates. Therefore, additional species presented in the solution can either be innocent or act as a coor- dination additive/buffer, a template, a counterion, and even a coligand. Taking these into consideration, the reaction outcomes can be more predictable 口那個(gè)地方是ff··· |

金蟲 (小有名氣)
| MAF合成對(duì)反應(yīng)條件相對(duì)不敏感,因?yàn)槿芤褐写嬖诘年庪x子和溶劑分子等常見的成分幾乎不能與靶金屬唑鍵競(jìng)爭(zhēng),由軟金屬離子和二唑組成的鍵尤其如此。然而,不同成分(包括不同唑類)之間的協(xié)調(diào)親和力不同。因此,溶液中存在的其他成分可能不起作用,也可能作為協(xié)調(diào)添加劑/緩沖劑、模板、反離子、甚至共同配體。如果將這些考慮進(jìn)去,反應(yīng)結(jié)果可能更具有可預(yù)測(cè)性。(azolate的翻譯不太確定) |
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