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[求助]
roaming dynamic是什么意思
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最近看文獻(xiàn) ,有這樣的詞匯roaming dynamic,但是不知道什么意思。關(guān)于這個(gè)理論有人知道是什么意思嗎? 以下的說(shuō)明供參考,A novel theoretical framework for predicting the branching between roaming and bond fission channels in molecular dissociations is described and applied to the decomposition of acetaldehyde。 During this roaming, the radicals may sample orientations where there is a barrierless path leading to the abstraction of a radical from one radical to the other. Most commonly, this abstraction involves the transfer of an H atom. Our own contribution to the treatment of roaming dynamics for ion-molecule reactions considered the multiple channels available from the [C2H2 · · ·CH4 +] ion molecule complex.4 |
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