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最新JACS文獻:Amorphous FeP2 and use as Anodes for Li-Ion Batteries
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低溫合成無定形的FeP2作為鋰電的負極材料,不過本文中其循環(huán)性一般,各位蟲友,能得到一些靈感哈... Reaction of Fe(N(SiMe3)2)3 with PH3 in THF at 100 °C gives amorphous FeP2 in high yield. As an anode material in a Li-ion battery, this material shows remarkable performance towards electrochemical lithiation/delithation, with gravimetric discharge and charge capacities of 1258 and 766 mAh/g, translating to 61% reversibility on the first cycle and a discharge capacity of 906 mAh/g after ten cycles, which translates to 66% retention of the theoretical full conversion capacity of FeP2 (1365 mAh/g). |
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