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求大有能力的人幫助,論文翻譯卡殼
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Complex 2 is a 3D open framework with 1D channel and crystallized in Cc. The asymmetric unit in 2 consists of one Mn(II), one doubly deprotonated HPIDC ligand, one coordinated water molecules and two lattice water molecule in Fig. 3. Mn(II) shows a distorted octahedral environment, coordinated by three HPIDC groups and one water molecule, as shown in Fig. 3. Among the three HPIDC ligand groups, one chelates Mn(II) in a N,O-mode to form a five-membered ring; the second HPIDC chelates the Mn(II) ion in an O,O0-mode to form a seven-membered ring, while the third HPIDC binds Mn(II) in a monodentate mode via one N atom of an pyriding ring. The MnAN distances range between 2.3031 and 2.4413 Å. These distances are longer than reported values [30]. The MnAO bonds range between 2.1347 and 2.2169 Å. These distances are comparable to reported values [30]. In each ligand HPIDC, the imidazole ring and pyridyl ring are almost coplanar with a dihedral angle of 13.6°。 |

至尊木蟲 (知名作家)
| 復合物2是一個具有一維通道的三維開放框架,并且在Cc中結晶。復合物2中的非對稱單位由一個Mn(II)、一個雙重去質子化的HPIDC配體、一個協作水分子和兩個格柵水分子組成,如圖3所示。Mn(II)顯示了一個彎曲的八面體環(huán)境,由三個HPIDC基團和一個水分子調控,如圖2所示。在三個HPIDC配體基團中,有一個以M,O-形式與Mn(II)螯合形成一個五元環(huán);第二個HPIDC以O,O-形式與Mn(II)離子形成七元環(huán);而第三個HPIDC通過吡啶環(huán)的一個N原子以單齒配體的形式結合Mn(II)。MnAN的距離介于2.3031和2.4413埃米(?)之間,比報道的值要大。MnAO鍵 的距離介于2.1347和2.2169埃米之間,與報道值差不多。在每個配體HPIDC中,咪唑環(huán)和吡啶環(huán)幾乎都是以二面角13.6度共面的。 |
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