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jjxiang捐助貴賓 (著名寫(xiě)手)
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[求助]
Suzuki反應(yīng)在高分子研究中的進(jìn)展
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本人才開(kāi)始研究高分子，急需Suzuki反應(yīng)在高分子研究中的進(jìn)展方面的文章�。�！金幣不是問(wèn)題，也歡迎和大家交流下這個(gè)方向�。”救瞬砰_(kāi)始，什么都不懂· ··· |
回復(fù)此樓» 收錄本帖的淘帖專輯推薦
 Suzuki Reaction |
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5樓2012-05-02 08:58:28
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2樓2012-05-01 11:44:49
shouwen
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【答案】應(yīng)助回帖
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感謝參與，應(yīng)助指數(shù) +1
jjxiang: 金幣+5 2012-05-01 22:16:11
感謝參與，應(yīng)助指數(shù) +1
jjxiang: 金幣+5 2012-05-01 22:16:11
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建議先看看這篇：J. POLYM. SCI. PART A: POLYM. CHEM. 39 1533–1556. The Tenth Anniversary of Suzuki Polycondensation (SPC) This article describes the successful transfer of the Suzuki cross-coupling (SCC) reaction to polymer synthesis, one of the major developments within the last decade of polymer synthesis. The polymers prepared by Suzuki polycondensation (SPC) and its Ni-catalyzed reductive counterpart are soluble and processable poly(arylene)s that, because of their rigid and conjugated backbones, are of interest for the materials sciences. Achievable molar masses easily compete with those of traditional polyesters and polyamides. This article also provides insight into some synthetic problems associated with the transfer of SCC from low molar mass organic chemistry to high molar mass polymer chemistry by addressing issues such as monomer purity,stoichiometric balance, achievable molar masses, and defects in the polymer structure. Although the emphasis of this article is synthetic and structural issues, some potential applications of the polyarylenes obtained are briefly mentioned. Together with the enormous developments in the areas of metallocene, ring-opening metathesis, and acyclic diene metathesis polymerization, the success of SPC impressingly underlines the increasing importance of transition-metal-catalyzed CC-bondforming reactions in polymer synthesis. |
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