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佳佳8905至尊木蟲 (正式寫手)
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[求助]
求助,急急急。!
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1 It should be confirmed that these mentioned intermolecular interactions are anion-pi interactions rather than van der Waals interactions or pi-pi interactions. For example, in 1, the distance of Cl1 anion to the tetrazole ring centroid is 3.360 A, which is equal to the sum of Cl1 anion and N atom of van der Waals radii. The separation distances between the Cl1 anion and the N atoms of the tetrazole ring are almost beyond 3.360 A. The sole observation of an anion-pi close contact should not be sufficient to justify presence of the anion-pi interaction. It should at least be accompanied by theoretical calculations. [ 來自科研家族 晶體材料家族 ] |
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至尊木蟲 (著名寫手)
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至尊木蟲 (正式寫手)
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