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[求助]
英語高手幫我翻譯一下 謝謝
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New Copper(II)complexes of indoxyl thiosemicarbazone(ITSC)show one pair of well defined reduction peaks at different potential in the forward scan,which represent the reduction of Cu++to Cu+by one electron process and subsequent oxidation of Cu+.The quasi- reversible nature of the Cu++/Cu+is due to inherent reducing tendency of thiosemicarbazone ligands. Ruthenium and cobalt complexes with Schiff bases bis-salicylaldehyde-o-phenylene-diaimine(saloph)and substituted(Cl,Br and NO2)oxidizeα-pinene into camphene,2,7,7-trimethyl ss pinene(3-oxatricyclo-4,1,1,o2,4-octane),2,3-epoxy,campholene aldehyde and D-verbenone.Ni(II)complexes with bidentate(NN)ligands become an efficient catalyst precursor for olefin oligomerisation in presence of an activator.A wide variety of cobalt(II)complexes are known to bind dioxygen more or less reversibly and are therefore frequently studied as model compounds for natural oxygen carrier and for their use in O2 storage,as well as in organic syntheses due to their catalytic properties under mild conditions. |
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