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11900490木蟲 (知名作家)
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三價金的晶體結(jié)構(gòu)
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http://onlinelibrary.wiley.com/doi/10.1002/anie.201209140/full 三價金的晶體結(jié)構(gòu) 圖片1.png Angewandte Chemie International EditionVolume 52, Issue 6, pages 1660-1663, 2 JAN 2013 DOI: 10.1002/anie.201209140http://onlinelibrary.wiley.com/d ... 201209140/full#fig1 A Missing Gold Link: An AuIII alkene complex has been prepared and characterized by NMR spectroscopy and X-ray crystallography. Its bonding features have been analyzed by DFT calculations and natural bond orbital (NBO) analysis. In [(cod)AuMe2]+, the unequal AuC bond lengths result from the domination of the preference of 1,5-cyclooctadiene (cod) for nonparallel double bonds over back donation from the metal which favors parallel double bonds. ncontent.gif [ Last edited by 11900490 on 2013-2-4 at 11:58 ] |
Sub-nano clusters(亞納米簇) |
找到一些相關(guān)的精華帖子,希望有用哦~
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