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bianlijing金蟲 (正式寫手)
樂天派
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[求助]
求翻譯成中文啊
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| Helical Rods: MOF-74. This structure is based on coordinated carboxyl and hydroxy groups. Helical Zn-O-C rods of composition [O2Zn2](CO2)2 are constructed from 6-coordinated Zn(II) centers, where each Zn has three carboxyl groups: one bound as in mode A and the remaining two as in A′.In addition, two hydroxy groups are bound as doubly bridging. The remaining coordination site has a terminal DMF ligand. The rods consist of edge-sharing ZnO6 octahedra alternately opposite and next-neighbor to form either a 31(1為下標) or a 32(2為下標) helix. The rods are linked by the benzene units of the DHBDC to produce bnn parallel rod packing and one-dimensional channels of dimensions 10.3 *5.5 Å2(2為上標) in which terminal DMF molecules protrude and water guests reside. Considering just the carboxylate C atoms as points of extension,they form 31(1為下標) and 32(2為下標) helices that are linked as in net etb . |

禁蟲 (文壇精英)
| 螺旋桿:MOF-74。這種結構是基于協(xié)調羧基和羥基。螺旋zn-o-c桿組成[ o2zn2 ](CO2)2是從基鋅(II)中心的構建,其中每個鋅三羧基:一為模式和剩下的兩個在′。此外,兩個羥基被綁定為雙架橋。剩余的協(xié)調網(wǎng)站有一個終端二甲基甲酰胺配體。棒由ZnO6八面體的邊緣共享交替相對的鄰居形成一個31(1為下標)或32(2為下標)螺旋。桿的dhbdc苯單元連接成BNN平行桿包裝,尺寸為10.3×5.5Å2一維通道(2為上標)中,終端的DMF分子和水突出客人居住?紤]到只是羧酸C原子點延伸,形成31(1為下標)和32(2為下標)螺旋連接在網(wǎng)絡傳輸。 |
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