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wb1988木蟲(chóng) (正式寫(xiě)手)
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[求助]
求Co3(PO4)2 8H2O 的cif文件
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如題,哪位好心人幫忙給發(fā)一下吧,謝啦 |

木蟲(chóng) (正式寫(xiě)手)

至尊木蟲(chóng) (知名作家)
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data_888-ICSD #?2008 by Fachinformationszentrum Karlsruhe, and the U.S. Secretary of #Commerce on behalf of the United States. All rights reserved. _database_code_ICSD 888 _audit_creation_date 1980/01/01 _chemical_name_systematic 'Cobalt Phosphate Hydrate' _chemical_formula_structural 'Co3 (P O4)2 (H2 O)' _chemical_formula_sum 'H2 Co3 O9 P2' _publ_section_title ; Crystal structure of cobalt(II) orthophosphate monohydrate, Co3 (P O4)2 H2 O ; loop_ _citation_id _citation_journal_abbrev _citation_year _citation_journal_volume _citation_page_first _citation_page_last _citation_journal_id_ASTM primary 'Inorganic Chemistry' 1976 15 2744 2748 INOCAJ _publ_author_name ; Anderson, J.;Kostiner, E.;Ruszala, F.A. ; _cell_length_a 9.523(3) _cell_length_b 7.903(2) _cell_length_c 9.294(3) _cell_angle_alpha 90. _cell_angle_beta 114.15(1) _cell_angle_gamma 90. _cell_volume 638.25 _cell_formula_units_Z 4 _symmetry_space_group_name_H-M 'P 1 21/c 1' _symmetry_Int_Tables_number 14 _refine_ls_R_factor_all .048 loop_ _symmetry_equiv_pos_site_id _symmetry_equiv_pos_as_xyz 1 'x, -y+.5, z+.5' 2 '-x, -y, -z' 3 '-x, y+.5, -z+.5' 4 'x, y, z' loop_ _atom_type_symbol _atom_type_oxidation_number Co2+ 2 H1+ 1 O2- -2 P5+ 5 loop_ _atom_site_label _atom_site_type_symbol _atom_site_symmetry_multiplicity _atom_site_Wyckoff_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_attached_hydrogens Co1 Co2+ 4 e 0.23973(8) 0.09126(9) 0.04641(8) 1. 0 Co2 Co2+ 4 e 0.13149(8) 0.11402(8) 0.10874(8) 1. 0 Co3 Co2+ 4 e 0.57227(8) 0.18256(8) 0.03214(8) 1. 0 P1 P5+ 4 e 0.1213(1) 0.4669(1) 0.2672(1) 1. 0 P2 P5+ 4 e 0.4928(1) 0.0128(1) 0.3008(1) 1. 0 O1 O2- 4 e 0.1434(4) 0.3756(4) 0.1325(4) 1. 0 O2 O2- 4 e 0.7900(4) 0.1354(5) 0.1879(4) 1. 0 O3 O2- 4 e 0.0498(4) 0.0103(5) 0.2788(4) 1. 0 O4 O2- 4 e 0.1756(4) 0.3470(5) 0.4113(4) 1. 0 O5 O2- 4 e 0.4627(4) 0.3403(5) 0.1168(4) 1. 0 O6 O2- 4 e 0.3363(4) 0.0725(4) 0.2918(4) 1. 0 O7 O2- 4 e 0.4896(4) -.0046(5) 0.1357(4) 1. 0 O8 O2- 4 e 0.6240(4) 0.1307(5) 0.4074(4) 1. 0 O9 O2- 4 e 0.8923(4) 0.3468(5) 0.4482(4) 1. 0 #Position of 8 Elements of H Are Undetermined. loop_ _atom_site_aniso_label _atom_site_aniso_type_symbol _atom_site_aniso_B_11 _atom_site_aniso_B_22 _atom_site_aniso_B_33 _atom_site_aniso_B_12 _atom_site_aniso_B_13 _atom_site_aniso_B_23 Co1 Co2+ 0.62(3) 0.48(3) 0.83(3) 0.03(2) 0.33(2) -.02(2) Co2 Co2+ 0.75(3) 0.45(3) 0.78(3) 0.00(2) 0.35(2) 0.04(2) Co3 Co2+ 0.77(3) 0.32(3) 0.91(3) 0.04(2) 0.47(2) -.04(2) P1 P5+ 0.61(4) 0.26(4) 0.72(4) -.02(3) 0.40(3) 0.00(3) P2 P5+ 0.53(4) 0.29(4) 0.71(4) 0.02(3) 0.35(3) -.01(3) O1 O2- 1.09(13) 0.43(12) 0.96(12) -.06(10) 0.65(11) -.18(10) O2 O2- 0.88(13) 0.51(13) 1.13(13) 0.03(10) 0.40(11) 0.13(10) O3 O2- 0.72(12) 0.81(13) 1.10(13) -.03(10) 0.52(11) -.08(10) O4 O2- 1.15(12) 0.34(13) 0.85(13) 0.15(10) 0.45(11) 0.26(10) O5 O2- 0.83(13) 0.37(12) 0.82(12) -.14(10) 0.28(10) -.14(10) O6 O2- 0.52(12) 0.93(13) 1.03(13) 0.11(10) 0.4(1) -.05(11) O7 O2- 1.00(13) 0.33(12) 0.74(12) -.23(9) 0.53(10) -.14(9) O8 O2- 0.72(12) 0.36(12) 0.89(12) -.09(9) 0.38(10) -.10(9) O9 O2- 0.94(13) 0.69(13) 1.08(13) 0.04(10) 0.63(11) 0.06(10) #End of data_888-ICSD |

至尊木蟲(chóng) (知名作家)
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data_65687-ICSD _database_code_ICSD 65687 _audit_creation_date 1990/06/08 _chemical_name_systematic 'Cobalt Phosphate Octahydrate' _chemical_formula_structural 'Co3 (P O4)2 (H2 O)8' _chemical_formula_sum 'H16 Co3 O16 P2' _publ_section_title ; Cobalt(II) orthophosphate octahydrate ; loop_ _citation_id _citation_journal_abbrev _citation_year _citation_journal_volume _citation_page_first _citation_page_last _citation_journal_id_ASTM primary 'Acta Crystallographica C (39,1983-)' 1989 45 1412 1413 ACSCEE _publ_author_name 'Riou, A.;Cudennec, Y.;Gerault, Y.' _cell_length_a 10.021(3) _cell_length_b 13.331(3) _cell_length_c 4.673(2) _cell_angle_alpha 90. _cell_angle_beta 104.90(6) _cell_angle_gamma 90. _cell_volume 603.28 _cell_formula_units_Z 2 _symmetry_space_group_name_H-M 'C 1 2/m 1' _symmetry_Int_Tables_number 12 _refine_ls_R_factor_all .018 loop_ _symmetry_equiv_pos_site_id _symmetry_equiv_pos_as_xyz 1 '-x, y, -z' 2 '-x, -y, -z' 3 'x, -y, z' 4 'x, y, z' 5 '-x+.5, y+.5, -z' 6 '-x+.5, -y+.5, -z' 7 'x+.5, -y+.5, z' 8 'x+.5, y+.5, z' loop_ _atom_type_symbol _atom_type_oxidation_number Co2+ 2 H1+ 1 O2- -2 P5+ 5 loop_ _atom_site_label _atom_site_type_symbol _atom_site_symmetry_multiplicity _atom_site_Wyckoff_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_occupancy _atom_site_attached_hydrogens _atom_site_B_iso_or_equiv Co1 Co2+ 2 a 0 0 0 1. 0 0 Co2 Co2+ 4 g 0 0.38993(2) 0 1. 0 0 P1 P5+ 4 i 0.31424(5) 0 0.3811(1) 1. 0 0 O1 O2- 4 i 0.1573(1) 0 0.3711(3) 1. 0 0 O2 O2- 4 i 0.3935(2) 0 0.7092(3) 1. 0 0 O3 O2- 8 j 0.3444(1) 0.09648(8) 0.2282(2) 1. 0 0 O4 O2- 8 j 0.4009(1) 0.38454(9) 0.1956(2) 1. 2 0 O5 O2- 8 j 0.1029(1) 0.2760(1) 0.2820(3) 1. 2 0 H1 H1+ 8 j 0.380(3) 0.411(2) 0.319(6) 1. 0 2. H2 H1+ 8 j 0.348(4) 0.372(2) 0.123(6) 1. 0 2. H3 H1+ 8 j 0.116(4) 0.299(2) 0.382(7) 1. 0 2. H4 H1+ 8 j 0.058(3) 0.221(2) 0.286(7) 1. 0 2. #End of data_65687-ICSD Sorry |

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