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liujiong1216
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[求助]
三價錳和四價錳只能和羧基或者咪唑基配位嗎?
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三價錳和四價錳只能和羧基或者咪唑基配位嗎? 文獻(xiàn)中說Mn(1) (指一個配合物中的一個錳) has six ligands: three μ3-O, one monodentate carboxylate, one bridging carboxylate and one imidazole ligand The ligands around Mn(1) are similar to what is found in manganese ions in manganese catalase enzymes. As usual, the coordination number, i.e., the number of nearest neighbors, for Mn(III) or (IV) is 6, and no other ligand could coordinate to it. 還是我理解錯了,文中的意思是說錳(III) or (IV) 的最大配位數(shù)是6,無法再多了? |
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