 |
 |
 |
 |
 |
 |
||
 |
 |
 |
 |
 |
| 查看: 3759 | 回復(fù): 95 | |||||||||
| 【獎勵】 本帖被評價83次，作者jiangyun2增加金幣 65.6 個 | |||||||||
jiangyun2榮譽(yù)版主 (文壇精英)
|
[資源]
Catalysts for Fine Chemical Synthesis
|
||||||||
|
Edited by Stanley M. Roberts and Jianliang Xiao University of Liverpool, UK John Whittall and Tom E. Pickett The Heath, Runcorn Stylacats Ltd, UK Contents Series Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xvii Preface to Volume 3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xix Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxi List of Chemical Names Used . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxiii 1 Considerations of Industrial Fine Chemical Synthesis 1 Mark W. Hooper . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.1 Introduction 1.2 Types of processes – flow charts . . . . . . . . . . . . . . . . . . . . . . . . 2 1.3 Costs associated with use of catalysts . . . . . . . . . . . . . . . . . . . . 3 2 Alkylation and Allylation Adjacent to a Carbonyl Group 13 2.1 The RuH2(CO)(PPh3)3-catalysed alkylation,alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage Fumitoshi Kakiuchi, Satoshi Ueno and Naoto Chatani . . . . . . . . . 14 2.2 Catalytic, asymmetric synthesis of a,a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst Michael North and Jose A. Fuentes . . . . . . . . . . . . . . . . . . . . . 21 2.3 Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts Barry Lygo and Benjamin I. Andrews . . . . . . . . . . . . . . . . . . . 27 3 Asymmetric Alkylation or Amination of Allylic Esters 35 3.1 Synthesis and application in palladium-catalysed asymmetric allylic substitution of enantiopure cyclic b-iminophosphine ligands， Maria Zablocka, Marek Koprowski, Jean-Pierre Majoral,Mathieu Achard and Ge′rard Buono . . . . . . . . . . . . . . . . . . . . . 36 3.2(9H,90H,10H,100H,11H,11H0,13H,130H,14H,140H,15H,150Hperfluorotricosane-12,120-diyl)bis[(4S)-4-phenyl-2-oxazoline as a ligand for asymmetric palladium catalysed alkylation of allylic acetates in fluorous media Je′roˆme Bayardon and Denis Sinou . . . . . . . . . . . . . . . . . . . . . 40 3.3 Facile synthesis of new axially chiral diphosphine complexes for asymmetric catalysis Matthias Lotz, Gernot Kramer, Katja Tappe and Paul Knochel 47 3.4 Chiral ferrocenyl-imino phosphines as ligands for palladium-catalysed enantioselective allylic alkylations Pierluigi Barbaro, Claudio Bianchini, Giuliano Giambastiani and Antonio Togni . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 4 Suzuki Coupling Reactions 59 4.1 Palladium-catalysed borylation and Suzuki coupling (BSC) to obtain b-benzothienyldehydroamino acid derivatives Ana S. Abreu, Paula M. T. Ferreira and Maria-Joa˜o R. P. Queiroz 60 4.2 Palladium-catalysed cross-coupling reactions of 4-tosylcoumarins and arylboronic acids: synthesis of 4-arylcoumarin compounds Jie Wu, Lisha Wang, Reza Fathi and Zhen Yang . . . . . . . . . . . . 64 4.3 Cyclopropyl arenes, alkynes and alkenes from the in situ generation of B-cyclopropyl-9-BBN and the Suzuki-Miyaura coupling of aryl, alkynyl and alkenyl bromides Ramon E. Huertas and John A. Soderquist . . . . . . . . . . . . . . . . 67 4.4 One-pot synthesis of unsymmetrical 1,3-dienes through palladium-catalysed sequential borylation of a vinyl electrophile by a diboron and cross-coupling with a distinct vinyl electrophile Tatsuo Ishiyama and Norio Miyaura . . . . . . . . . . . . . . . . . . . . 70 4.5 Pd(OAc)2/2-Aryl oxazoline catalysed Suzuki coupling reactions of aryl bromides and boronic acids Bin Tao and David W. Boykin . . . . . . . . . . . . . . . . . . . . . . . . . 74 4.6 Palladium-catalysed reactions of haloaryl phosphine oxides: modular routes to functionalised ligands Colin Baillie, Lijin Xu and Jianliang Xiao . . . . . . . . . . . . . . . . 77 4.7 Bulky electron rich phosphino-amines as ligands for the Suzuki coupling reaction of aryl chlorides Matthew L. Clarke and J. Derek Woollins . . . . . . . . . . . . . . . . 81 4.8 Arylation of ketones, aryl amination and Suzuki-Miyaura cross coupling using a well-defined palladium catalyst bearing an N-heterocyclic carbene ligand Nicholas Marion, Oscar Navarro, Roy A. Kelly III and Steven P. Nolan . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 5 Heck Coupling Reactions 91 5.1 Palladium-catalysed multiple and asymmetric arylations of vinyl ethers carrying co-ordinating nitrogen auxiliaries: synthesis of arylated ketones and aldehydes Peter Nilsson and Mats Larhed . . . . . . . . . . . . . . . . . . . . . . . . 92 5.2 Palladium-catalysed highly regioselective arylation of electron-rich olefins Lijin Xu, Jun Mo and Jianliang Xiao . . . . . . . . . . . . . . . . . . . . 100 5.3 1-[4-(S)-tert-Butyl-2-oxazolin-2-yl]-2-(S)-(diphenylphosphino) ferrocene as a ligand for the palladium-catalysed intermolecular asymmetric Heck reaction of 2,3-dihydrofuran Tim G. Kilroy, Yvonne M. Malone and Patrick J. Guiry . . . . . . . 104 CONTENTS ix 6 Sonogashira Coupling Reactions 113 6.1 Nonpolar biphasic catalysis: Suzuki- and Sonogashira coupling reactions Anupama Datta and Herbert Plenio . . . . . . . . . . . . . . . . . . . 113 6.2 Polystyrene-supported soluble palladacycle catalyst as recyclable catalyst for Heck, Suzuki and Sonogashira reactions Chih-An Lin and Fen-Tair Luo . . . . . . . . . . . . . . . . . . . . . . . 116 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 Reference . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 7 Cross-Coupling Reactions 127 7.1 Cross-coupling reaction of alkyl halides with Grignard reagents in the presence of 1,3-butadiene catalysed by nickel, palladium, or copper Jun Terao and Nobuaki Kambe . . . . . . . . . . . . . . . . . . . . . . . 128 7.2 Triorganoindium compounds as efficient reagents for palladium-catalysed cross-coupling reactions with aryl and vinyl electrophiles Luis A. Sarandeses and Jose′ Pe′rez Sestelo . . . . . . . . . . . . . . . 133 7.3 Cross-coupling reactions catalysed by heterogeneous nickel-on-charcoal Bryan A. Frieman and Bruce H. Lipshutz . . . . . . . . . . . . . . . . 138 7.4 Carbon-carbon bond formation using arylboron reagents with rhodium(I) catalysts in aqueous media John Mancuso, Masahiro Yoshida and Mark Lautens . . . . . . . 147 8 Regioselective or Asymmetric 1,2-Addition to Aldehydes 155 8.1 Development of a highly regioselective metal-mediated allylation reaction in aqueous media Kui-Thong Tan, Shu-Sin Chng, Hin-Soon Cheng and Teck-Peng Loh 156 8.2 Boronic acids as aryl source for the catalysed enantioselective aryl transfer to aldehydes Jens Rudolph and Carsten Bolm . . . . . . . . . . . . . . . . . . . . . . 161 8.3 Jacobsen’s Salen as a chiral ligand for the chromium-catalysed addition of 3-chloro-propenyl pivalate to aldehydes: a catalytic asymmetric entry to syn-alk-1-ene-3,4-diols Marco Lombardo, Sebastiano Licciulli, Stefano Morganti and Claudio Trombini . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164 9 Olefin Metathesis Reactions 169 9.1 Highly active ruthenium (pre)catalysts for metathesis reactions Syuzanna Harutyunyan, Anna Michrowska and Karol Grela . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169 9.2 A highly active and readily recyclable olefin metathesis catalyst Stephen J. Connon, Aideen M. Dunne and Siegfried Blechert 174 9.3 Stereoselective synthesis of L-733,060 G. Bhaskar and B. Venkateswara Rao . . . . . . . . . . . . . . . . . . 178 10 Cyclisation Reactions 181 10.1 Molecular sieves as promoters for the catalytic Pauson-Khand reaction Jaime Blanco-Urgoiti, Gema Domı′nguez and Javier Pe′rez-Castells . . . . . . . . . . . . . . . . . . . . . . . . . . 182 10.2 Palladium(II)-catalysed cyclization of alkynes with aldehydes, ketones or nitriles initiated by acetoxypalladation of alkynes Ligang Zhao and Xiyan Lu . . . . . . . . . . . . . . . . . . . . . . . . . 185 10.3 Rhodium(I)-catalysed intramolecular alder-ene reaction and syntheses of functionalised a-methylene-g-butyrolactones and cyclopentanones Minsheng He, Aiwen Lei and Xumu Zhang . . . . . . . . . . . . . . 190 10.4 Rhodium-catalysed [2 t 2 t 2] cyclotrimerisation in an aqueous–organic biphasic system Hiroshi Shinokubo and Koichiro Oshima . . . . . . . . . . . . . . . 193 10.5 Titanocene-catalysed transannular cyclisation of epoxygermacrolides: enantiospecific synthesis of eudesmanolides Antonio Rosales, Juan M. Cuerva and J. Enrique Oltra . . . . . 196 11 Asymmetric Aldol and Michael Reactions 201 11.1 Direct catalytic asymmetric aldol reaction of a a-hydroxyketone promoted by an Et2Zn/linked-BINOL complex Masakatsu Shibasaki, Shigeki Matsunaga and Naoya Kumagai 202 11.2 Highly enantioselective direct aldol reaction catalysed by a novel small organic molecule Zhuo Tang, Liu-Zhu Gong, Ai-Qiao Mi and Yao-Zhong Jiang 208 11.3 Direct catalytic asymmetric Michael reaction of a-hydroxyketone promoted by Et2Zn/linked-BINOL complex Masakatsu Shibasaki, Shigeki Matsunaga and Naoya Kumagai 210 11.4 Catalytic enantioselective Michael reaction catalysed by well-defined chiral ruthenium-amido complexes Masahito Watanabe, Kunihiko Murata, and Takao Ikariya . . . 216 12 Stereoselective Hydroformylation, Carbonylation and Carboxylation Reactions 225 12.1 Ortho-diphenylphosphanylbenzoyl-(o-DPPB) directed diastereoselective hydroformylation of allylic alcohols Bernhard Breit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226 12.2 The synthesis and application of ESPHOS: A new diphosphorus ligand for the hydroformylation of vinyl acetate Martin Wills and Simon W. Breeden . . . . . . . . . . . . . . . . . . . 230 12.3 Platinum-catalysed asymmetric hydroformylation of styrene Submitted by Stefa′nia Csere′pi-Szu¨cs and Jo′zsef Bakos . . . . . . 238 12.4 Phosphine-free dimeric palladium (II) complex for the carbonylation of aryl iodides C. Ramesh, Y. Kubota and Y. Sugi . . . . . . . . . . . . . . . . . . . . 244 12.5 Carboxylation of pyrrole to pyrrole-2-carboxylate by cells of Bacillus megaterium in supercritical carbon dioxide Tomoko Matsuda, Tadao Harada, Toru Nagasawa and Kaoru Nakamura . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247 [ 來自小組 狼族傳說 ] [ Last edited by jiangyun2 on 2013-9-19 at 18:44 ] |
回復(fù)此樓» 本帖附件資源列表
-
歡迎監(jiān)督和反饋：小木蟲僅提供交流平臺，不對該內(nèi)容負(fù)責(zé)。
本內(nèi)容由用戶自主發(fā)布，如果其內(nèi)容涉及到知識產(chǎn)權(quán)問題，其責(zé)任在于用戶本人，如對版權(quán)有異議，請聯(lián)系郵箱：xiaomuchong@tal.com - 附件 1 : Catalysts_for_Fine_Chemical_Synthesis_Vol_3.pdf
2013-09-19 17:48:55, 2.35 M
» 收錄本帖的淘帖專輯推薦
 萬卷閣之搜神記 | 精品資源 | 小木蟲環(huán)境治理 | 催化 |
| 催化 |
» 猜你喜歡
2026湖北師范大學(xué)化學(xué)化工學(xué)院招收碩士研究生調(diào)劑
已經(jīng)有0人回復(fù)
-
2026湖北師范大學(xué)化學(xué)化工學(xué)院招收研究生調(diào)劑
已經(jīng)有0人回復(fù)
-
專業(yè)論文潤色/翻譯怎么收費(fèi)?
已經(jīng)有285人回復(fù)
-
26年材料/化學(xué)相關(guān)專業(yè)博士研究生招生 溫州大學(xué)化學(xué)與材料工程學(xué)院(26年秋季入學(xué))
已經(jīng)有0人回復(fù)
-
0703調(diào)劑
已經(jīng)有2人回復(fù)
-
085602化學(xué)工程求調(diào)劑。
已經(jīng)有4人回復(fù)
-
2026年博士研究生招生
已經(jīng)有1人回復(fù)
-
304求調(diào)劑
已經(jīng)有6人回復(fù)
-
國家工程物理交叉科學(xué)研究中心招收凝聚態(tài)物理及相關(guān)專業(yè)碩士研究生一名
已經(jīng)有8人回復(fù)
» 本主題相關(guān)價值貼推薦，對您同樣有幫助:
- 化學(xué)類電子書，291本，要的收藏�！驹瓌�(chuàng)】
已經(jīng)有370人回復(fù)
- 【資源】催化的世界里那些Super Masters和那些Classic Reviews
已經(jīng)有5人回復(fù)
- 09年晶體牛人名家實(shí)驗(yàn)室鏈接介紹(回帖有金幣)
已經(jīng)有161人回復(fù)
40樓2013-11-26 06:40:30
簡單回復(fù)
白慕水2樓
2013-09-19 21:22
回復(fù)
五星好評 
一溪霜月3樓
2013-09-20 07:41
回復(fù)
五星好評 頂一下，感謝分享！
2013-09-20 08:30
回復(fù)
五星好評 頂一下，感謝分享！
zxw19825樓
2013-09-20 10:00
回復(fù)
五星好評 頂一下，感謝分享！
philifer6樓
2013-09-20 17:45
回復(fù)
五星好評 頂一下，感謝分享！
zxo12347樓
2013-09-21 03:39
回復(fù)
五星好評 頂一下，感謝分享！
2013-09-21 11:10
回復(fù)
五星好評 謝謝分享！ [ 發(fā)自小木蟲客戶端 ]
lsgui9樓
2013-09-21 11:52
回復(fù)
五星好評 頂一下，感謝分享！
kinkilyou10樓
2013-09-21 12:36
回復(fù)
五星好評 頂一下，感謝分享！
304212806011樓
2013-09-21 13:46
回復(fù)
五星好評 頂一下，感謝分享！
gaussfan12樓
2013-09-21 16:44
回復(fù)
五星好評 頂一下，感謝分享！
tjk13樓
2013-09-21 17:04
回復(fù)
五星好評 頂一下，感謝分享！
liuque14樓
2013-09-21 17:07
回復(fù)
五星好評 頂一下，感謝分享！
wtiger15樓
2013-09-21 21:09
回復(fù)
五星好評 頂一下，感謝分享！
wjh666816樓
2013-09-21 21:18
回復(fù)
五星好評 頂一下，感謝分享！
wtiger17樓
2013-09-21 21:19
回復(fù)
頂一下，感謝分享！
cqmqc18樓
2013-09-21 21:27
回復(fù)
五星好評 頂一下，感謝分享！
chinguo19樓
2013-09-21 21:41
回復(fù)
五星好評 頂一下，感謝分享！
wcj66889920樓
2013-09-22 03:46
回復(fù)
五星好評 頂一下，感謝分享！
zch668200321樓
2013-09-22 05:17
回復(fù)
五星好評 頂一下，感謝分享！
陳昭智22樓
2013-09-22 07:29
回復(fù)
五星好評 頂一下，感謝分享！
yanzr23樓
2013-09-22 07:49
回復(fù)
五星好評 頂一下，感謝分享！
gwxgwc24樓
2013-09-22 08:13
回復(fù)
五星好評 頂一下，感謝分享！
dudubaobao25樓
2013-09-22 10:01
回復(fù)
五星好評 頂一下，感謝分享！
hanjh0501a26樓
2013-09-22 10:52
回復(fù)
五星好評 頂一下，感謝分享！
chemphys27樓
2013-09-22 11:19
回復(fù)
三星好評 頂一下，感謝分享！
lwg328樓
2013-09-22 11:31
回復(fù)
五星好評 頂一下，感謝分享！
#小呆#29樓
2013-09-22 14:18
回復(fù)
五星好評 頂一下，感謝分享！
gate_open30樓
2013-09-22 16:08
回復(fù)
五星好評 頂一下，感謝分享！
shouyongzhou31樓
2013-09-22 16:13
回復(fù)
五星好評 頂一下，感謝分享！
muxinjin32樓
2013-09-22 16:14
回復(fù)
五星好評 頂一下，感謝分享！
hexuetao33樓
2013-09-22 16:41
回復(fù)
五星好評 頂一下，感謝分享！
bushII34樓
2013-09-22 17:15
回復(fù)
五星好評 頂一下，感謝分享！
icemanok35樓
2013-09-22 17:48
回復(fù)
五星好評 頂一下，感謝分享！
exuan136樓
2013-09-22 18:44
回復(fù)
五星好評 頂一下，感謝分享！
cpu_huang37樓
2013-11-10 21:35
回復(fù)
五星好評 頂一下，感謝分享！
我是個大盜賊38樓
2013-11-12 17:28
回復(fù)
五星好評 頂一下，感謝分享！
zlj_love39樓
2013-11-18 21:22
回復(fù)
五星好評 頂一下，感謝分享！
rwsh60341樓
2014-01-04 11:24
回復(fù)
五星好評 頂一下，感謝分享！
火神的右耳42樓
2014-01-14 20:46
回復(fù)
五星好評 頂一下，感謝分享！
ljc05051243樓
2014-01-16 21:12
回復(fù)
五星好評 頂一下，感謝分享！
2014-01-18 15:39
回復(fù)
五星好評 頂一下，感謝分享！
kingki45樓
2014-01-20 02:13
回復(fù)
五星好評
52565332446樓
2014-01-20 11:00
回復(fù)
五星好評 頂一下，感謝分享！
linuxx47樓
2014-02-10 10:05
回復(fù)
五星好評 頂一下，感謝分享！
lixianwei48樓
2014-02-17 11:18
回復(fù)
五星好評 頂一下，感謝分享！
火神的右耳49樓
2014-02-17 21:44
回復(fù)
頂一下，感謝分享！
化學(xué)愛者00750樓
2014-02-21 20:10
回復(fù)
五星好評 頂一下，感謝分享！
相關(guān)版塊跳轉(zhuǎn)
我要訂閱樓主 jiangyun2 的主題更新
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 394求調(diào)劑 +3 | 好事多磨靜候佳?/a> 2026-03-26 | 5/250 |
|
|---|---|---|---|---|
|
[考研] 材料求調(diào)劑 +9 | @taotao 2026-03-21 | 9/450 |
|
|
|
[考研] 0856，材料與化工321分求調(diào)劑 +12 | 大饞小子 2026-03-27 | 13/650 |
|
|
|
[考研]
 材料與化工考研調(diào)劑
+17
|
孅華 2026-03-22 | 17/850 |
|
|
|
[有機(jī)交流]
高溫高壓反應(yīng)求助
 10+4
|
chibby 2026-03-25 | 4/200 |
|
|
|
[考研] 266分求材料化工冶金礦業(yè)等專業(yè)的調(diào)劑 +4 | 哇呼哼呼哼 2026-03-26 | 4/200 |
|
|
|
[考研] 07化學(xué)280分求調(diào)劑 +10 | 722865 2026-03-23 | 10/500 |
|
|
|
[考研] 材料292調(diào)劑 +12 | 橘頌思美人 2026-03-23 | 12/600 |
|
|
|
[考研] 一志愿華東理工大學(xué)081700，初試分?jǐn)?shù)271 +6 | kotoko_ik 2026-03-23 | 7/350 |
|
|
|
[考研] 316求調(diào)劑 +5 | Pigcasso 2026-03-24 | 5/250 |
|
|
|
[考研] 334求調(diào)劑 +3 | 雨清天晴 2026-03-21 | 3/150 |
|
|
|
[考研] 342求調(diào)劑 +3 | 加油a李zs 2026-03-26 | 3/150 |
|
|
|
[考研] 081200-11408-276學(xué)碩求調(diào)劑 +3 | 崔wj 2026-03-26 | 3/150 |
|
|
|
[考研] 生物學(xué) 296 求調(diào)劑 +4 | 朵朵- 2026-03-26 | 6/300 |
|
|
|
[考研] 299求調(diào)劑 +4 | 15188958825 2026-03-25 | 4/200 |
|
|
|
[考研] 303求調(diào)劑 +6 | 藍(lán)山月 2026-03-25 | 6/300 |
|
|
|
[考研] 一志愿南航 335分 | 0856材料化工 | GPA 4.07 | 有科研經(jīng)歷 +6 | cccchenso 2026-03-23 | 6/300 |
|
|
|
[考研] 292求調(diào)劑 +4 | 鵝鵝鵝額額額額?/a> 2026-03-24 | 4/200 |
|
|
|
[考研] 300求調(diào)劑，材料科學(xué)英一數(shù)二 +5 | leaflight 2026-03-24 | 5/250 |
|
|
|
[考研] 070300，一志愿北航320求調(diào)劑 +3 | Jerry0216 2026-03-22 | 5/250 |
|