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cauc_yx銅蟲 (小有名氣)
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[求助]
Ni的磁矩的計算結(jié)果為什么不對? 已有1人參與
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紅色是我的計算結(jié)果,和參考材料的準確值0.6,相去甚遠啊。 +-------------------------------------------------+ | | | CCC AA SSS TTTTT EEEEE PPPP | | C A A S T E P P | | C AAAA SS T EEE PPPP | | C A A S T E P | | CCC A A SSS T EEEEE P | | | +-------------------------------------------------+ | | | Welcome to Materials Studio CASTEP version 4.4 | | Ab Initio Total Energy Program | | | | Authors: | | M. Segall, M. Probert, C. Pickard, P. Hasnip, | | S. Clark, K. Refson, M. Payne | | | | Contributors: | | P. Lindan, P. Haynes, J. White, V. Milman, | | N. Govind, M. Gibson, P. Tulip, V. Cocula, | | B. Montanari, D. Quigley, M. Glover, | | L. Bernasconi, A. Perlov, M. Plummer | | | | Copyright (c) 2000 - 2008 | | | | Please cite | | | | "First principles methods using CASTEP" | | | | Zeitschrift fuer Kristallographie | | 220(5-6) pp. 567-570 (2005) | | | | S. J. Clark, M. D. Segall, C. J. Pickard, | | P. J. Hasnip, M. J. Probert, K. Refson, | | M. C. Payne | | | | in all publications arising from | | your use of CASTEP | | | +-------------------------------------------------+ This version was compiled for win32 on Nov 14 2008 License checkout of MS_castep successful Pseudo atomic calculation performed for Ni 3d8 4s2 Converged in 37 iterations to a total energy of -1347.0378 eV Calculation parallelised over 1 nodes. K-points are distributed over 1 groups, each containing 1 nodes. ************************************ Title ************************************ CASTEP calculation from Materials Studio ***************************** General Parameters ****************************** output verbosity : normal (1) write checkpoint data to : Ni.check type of calculation : single point energy stress calculation : off density difference calculation : off electron localisation func (ELF) calculation : off unlimited duration calculation timing information : on memory usage estimate : on write final potential to formatted file : off write final density to formatted file : off output length unit : A output mass unit : amu output time unit : ps output charge unit : e output energy unit : eV output force unit : eV/A output velocity unit : A/ps output pressure unit : GPa output inv_length unit : 1/A output frequency unit : cm-1 output force constant unit : eV/A**2 output volume unit : A**3 output IR intensity unit : (D/A)**2/amu output dipole unit : D output efield unit : eV/A/e wavefunctions paging : none random number generator seed : randomised (194854109) data distribution : optimal for this architecture optimization strategy : balance speed and memory *********************** Exchange-Correlation Parameters *********************** using functional : Perdew Burke Ernzerhof Divergence correction : off ************************* Pseudopotential Parameters ************************** pseudopotential representation : reciprocal space <beta|phi> representation : reciprocal space **************************** Basis Set Parameters ***************************** basis set accuracy : FINE plane wave basis set cut-off : 300.0000 eV size of standard grid : 2.0000 largest prime factor in FFT : 5 finite basis set correction : none **************************** Electronic Parameters **************************** number of electrons : 10.00 net charge of system : 0.000 net spin of system : 2.000 number of up spins : 6.000 number of down spins : 4.000 treating system as spin-polarized number of bands : 6 ********************* Electronic Minimization Parameters ********************** Method: Treating system as non-metallic, and number of SD steps : 1 and number of CG steps : 4 total energy / atom convergence tol. : 0.1000E-05 eV max force / atom convergence tol. : ignored convergence tolerance window : 3 cycles max. number of SCF cycles : 200 ******************************************************************************* ------------------------------- Unit Cell ------------------------------- Real Lattice(A) Reciprocal Lattice(1/A) 0.0000000 1.7620000 1.7620000 -1.7829697 1.7829697 1.7829697 1.7620000 0.0000000 1.7620000 1.7829697 -1.7829697 1.7829697 1.7620000 1.7620000 0.0000000 1.7829697 1.7829697 -1.7829697 Lattice parameters(A) Cell Angles a = 2.491844 alpha = 60.000000 b = 2.491844 beta = 60.000000 c = 2.491844 gamma = 60.000000 Current cell volume = 10.940765 A**3 ------------------------------- Cell Contents ------------------------------- Total number of ions in cell = 1 Total number of species in cell = 1 Max number of any one species = 1 xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx x Element Atom Fractional coordinates of atoms x x Number u v w x x----------------------------------------------------------x x Ni 1 0.000000 0.000000 0.000000 x xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx No user defined ionic velocities ------------------------------- Details of Species ------------------------------- Mass of species in AMU Ni 58.7099991 Electric Quadrupole Moment (Barn) Ni 0.1620000 Isotope 61 Files used for pseudopotentials: Ni Ni_00PBE.uspcc ------------------------------- k-Points For BZ Sampling ------------------------------- MP grid size for SCF calculation is 12 12 12 Number of kpoints used = 182 +++++++++++++++++++++++++++++++++++++++++++++++++++++++ + Number Fractional coordinates Weight + +-----------------------------------------------------+ + 1 0.458333 0.458333 0.458333 0.0011574 + + 2 0.458333 0.458333 0.375000 0.0034722 + + 3 0.458333 0.458333 0.291667 0.0034722 + + 4 0.458333 0.458333 0.208333 0.0034722 + + 5 0.458333 0.458333 0.125000 0.0034722 + + 6 0.458333 0.458333 0.041667 0.0034722 + + 7 0.458333 0.458333 -0.041667 0.0034722 + + 8 0.458333 0.458333 -0.125000 0.0034722 + + 9 0.458333 0.458333 -0.208333 0.0034722 + + 10 0.458333 0.458333 -0.291667 0.0034722 + + 11 0.458333 0.458333 -0.375000 0.0034722 + + 12 0.458333 0.458333 -0.458333 0.0034722 + + 13 0.458333 0.375000 0.375000 0.0034722 + + 14 0.458333 0.375000 0.291667 0.0069444 + + 15 0.458333 0.375000 0.208333 0.0069444 + + 16 0.458333 0.375000 0.125000 0.0069444 + + 17 0.458333 0.375000 0.041667 0.0069444 + + 18 0.458333 0.375000 -0.041667 0.0069444 + + 19 0.458333 0.375000 -0.125000 0.0069444 + + 20 0.458333 0.375000 -0.208333 0.0069444 + + 21 0.458333 0.375000 -0.291667 0.0069444 + + 22 0.458333 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0.125000 0.125000 -0.125000 0.0034722 + + 177 0.125000 0.041667 0.041667 0.0034722 + + 178 0.125000 0.041667 -0.041667 0.0069444 + + 179 0.125000 0.041667 -0.125000 0.0069444 + + 180 0.125000 -0.041667 -0.041667 0.0034722 + + 181 0.041667 0.041667 0.041667 0.0011574 + + 182 0.041667 0.041667 -0.041667 0.0034722 + +++++++++++++++++++++++++++++++++++++++++++++++++++++++ ------------------------------- Symmetry and Constraints ------------------------------- Number of symmetry operations = 48 There are no ionic constraints specified or generated for this cell Set iprint > 1 for details on symmetry rotations/translations Centre of mass is NOT constrained Number of cell constraints= 5 Cell constraints are: 1 1 1 0 0 0 External pressure/stress (GPa) 0.00000 0.00000 0.00000 0.00000 0.00000 0.00000 +---------------- MEMORY AND SCRATCH DISK ESTIMATES PER NODE -----------------+ | Memory Disk | | Model and support data 27.3 MB 4.4 MB | | Electronic energy minimisation requirements 13.3 MB 13.8 MB | | ----------------------------- | | Approx. total storage required per node 40.6 MB 18.2 MB | | | | Requirements will fluctuate during execution and may exceed these estimates | +-----------------------------------------------------------------------------+ ------------------------------------------------------------------------ <-- SCF SCF loop Energy Energy gain Timer <-- SCF per atom (sec) <-- SCF ------------------------------------------------------------------------ <-- SCF Initial -7.87857485E+002 3.74 <-- SCF 1 -1.34659685E+003 5.58739367E+002 16.10 <-- SCF 2 -1.35148362E+003 4.88676433E+000 28.44 <-- SCF 3 -1.35217162E+003 6.88002549E-001 40.75 <-- SCF 4 -1.35239175E+003 2.20129659E-001 52.96 <-- SCF 5 -1.35247788E+003 8.61291228E-002 65.18 <-- SCF 6 -1.35251505E+003 3.71681185E-002 77.38 <-- SCF 7 -1.35253889E+003 2.38443920E-002 89.58 <-- SCF 8 -1.35255300E+003 1.41145620E-002 101.78 <-- SCF 9 -1.35256279E+003 9.78524128E-003 113.97 <-- SCF 10 -1.35256913E+003 6.33974261E-003 126.19 <-- SCF 11 -1.35257485E+003 5.71970404E-003 138.37 <-- SCF 12 -1.35257691E+003 2.05801587E-003 150.85 <-- SCF 13 -1.35257871E+003 1.79999011E-003 163.32 <-- SCF 14 -1.35257978E+003 1.07319251E-003 175.53 <-- SCF 15 -1.35258090E+003 1.12067003E-003 187.72 <-- SCF 16 -1.35258166E+003 7.53550865E-004 199.95 <-- SCF 17 -1.35258227E+003 6.13623831E-004 212.16 <-- SCF 18 -1.35258276E+003 4.88358974E-004 224.36 <-- SCF 19 -1.35258313E+003 3.70552981E-004 236.54 <-- SCF 20 -1.35258341E+003 2.85483860E-004 249.01 <-- SCF 21 -1.35258370E+003 2.89331790E-004 261.21 <-- SCF 22 -1.35258383E+003 1.30725320E-004 273.66 <-- SCF 23 -1.35258390E+003 7.05266415E-005 286.29 <-- SCF 24 -1.35258418E+003 2.75982060E-004 298.76 <-- SCF 25 -1.35258423E+003 4.77462605E-005 311.94 <-- SCF 26 -1.35258431E+003 8.32664598E-005 324.12 <-- SCF 27 -1.35258436E+003 4.80255204E-005 336.34 <-- SCF 28 -1.35258442E+003 6.52373162E-005 348.54 <-- SCF 29 -1.35258445E+003 2.23413917E-005 361.27 <-- SCF 30 -1.35258448E+003 3.31297366E-005 373.47 <-- SCF 31 -1.35258451E+003 2.94414197E-005 385.70 <-- SCF 32 -1.35258453E+003 2.00468299E-005 398.46 <-- SCF 33 -1.35258453E+003 0.00000000E+000 413.32 <-- SCF 34 -1.35258453E+003 3.86697033E-013 428.24 <-- SCF ------------------------------------------------------------------------ <-- SCF 2*Integrated Spin Density = 2.00000 2*Integrated |Spin Density| = 2.00000 Final energy = -1352.584528841 eV (energy not corrected for finite basis set) |
新蟲 (初入文壇)
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進行能量計算時,你那段的后面還應(yīng)有下面一段文字,這里面的 Hirshfeld Analysis 部分才是正確的算出的Ni原子的磁矩 Writing analysis data to NiSpin2U0.castep_bin Writing model to NiSpin2U0.check ***************** Symmetrised Forces ***************** * * * Cartesian components (eV/A) * * -------------------------------------------------- * * x y z * * * * Ni 1 0.00000 0.00000 0.00000 * * Ni 2 -0.00000 -0.00000 0.00000 * * Ni 3 -0.00000 0.00000 -0.00000 * * Ni 4 -0.00000 0.00000 0.00000 * * * ****************************************************** Pseudo atomic calculation performed for Ni 3d8 4s2 Converged in 37 iterations to a total energy of -1340.6170 eV Charge spilling parameter for spin component 1 = 0.12% Charge spilling parameter for spin component 2 = 0.17% Atomic Populations (Mulliken) ----------------------------- Species Ion s p d f Total Charge (e) Spin (hbar/2) =========================================================================== Ni 1 0.55 0.79 8.66 0.00 10.00 0.00 0.57 Ni 2 0.55 0.79 8.66 0.00 10.00 0.00 0.57 Ni 3 0.55 0.79 8.66 0.00 10.00 0.00 0.57 Ni 4 0.55 0.79 8.66 0.00 10.00 0.00 0.57 =========================================================================== Bond Population Spin Length (A) ====================================================================== Ni 3 -- Ni 4 0.02 0.03 2.44417 Ni 2 -- Ni 4 0.02 0.03 2.44417 Ni 2 -- Ni 3 0.02 0.03 2.44417 Ni 1 -- Ni 4 0.02 0.03 2.44417 Ni 1 -- Ni 3 0.02 0.03 2.44417 Ni 1 -- Ni 2 0.02 0.03 2.44417 ====================================================================== Hirshfeld Analysis ------------------ Species Ion Hirshfeld Charge (e) Spin (hbar/2) =================================================== Ni 1 -0.00 0.57 Ni 2 0.00 0.57 Ni 3 -0.00 0.57 Ni 4 0.00 0.57 =================================================== Writing analysis data to NiSpin2U0.castep_bin Writing model to NiSpin2U0.check A BibTeX formatted list of references used in this run has been written to NiSpin2U0.bib Initialisation time = 1.59 s Calculation time = 12.46 s Finalisation time = 0.09 s Total time = 14.15 s Overall parallel efficiency rating: Poor (49%) Data was distributed by:- G-vector (2-way); efficiency rating: Good (71%) k-point (4-way); efficiency rating: Satisfactory (61%) Parallel notes: 1) Calculation only took 14.2 s, so efficiency estimates may be inaccurate. |
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