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touchhappy金蟲 (著名寫手)
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(技術貼)An introduction to reptation theory 已有13人參與
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Reptation?????? ???дд??????????????????????????????????????????????????????κ?????????????????? ![]() ![]() ![]() ??????????????????????????о????ε???磬?????????????????????Flory??Kuhn??Debye??Rouse??Zimm??????Щ?????????????????????????????????????????????????????????????????????????????е?polymer chain??isolated chain?????????????????????????????????????????????????????????У???????????????м?????????????????????????????????????????terminology???????????ν?????????????????????????????????ì???????????????????????????????????????????????????????????????????С??????????????????????????????????????????????????????????????????????????????????universality?????????????????????????????????????????3.4?η???????universality????????????????????????????????????????????????ж??????????????????????????????????????????????reptation?????????????????????de gennes??S.F Edwards??M.Doi?? Reptation???????????????????Σ???????壬????????????????????????????е????????????????????????????????????????????????????contour length???????????????????????reptation?????????????????????????????????????????????????????????????????target chain???????tube?е???????????tube?????????????Χ???????????????????????????????????????????????????????de gennes???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????к?????????????????????????????????????de gennes??????????????????????????????????????????????????????????????????????????????γ??????????????????????????????????????????????diameter??????a????????磨mesh size????????????????????????mesh size????????????????????????????????????mesh size?????????λ?????????rescaling??????ν??blob scaling??????????????????????????С?a??blob??????????????????????????????????????λ???????????????????????????????????????????????????? scaling??de gennes????ü????????????????????????????????????????????????????У????????????????任?????????????????????????????ǹ??????????????δ??????????????????????????????????????????????????е?????????????????????????е??????????????ó???????????????????????ɡ?????????????thermal blob???仮???????????blob????????kT?????????????????????????scaling???????????????????????м???blob?????м???KT?? ??????????????????????????????relaxation function????????????????????????????????????response??????ν???????????????????????С????????linear regime???????????????????????????????????????????reptile-like motion????????????????????????????????????????????????????~N?????η?????????????????????tube??chain??blob size????????????????????????Rouse??????????????~N?????????????????????????????????????????????????е??????????????????е????????? ????????????????????????????????????ν??contour length fluctuation??constrain release????????????????????????????????Z??????????blob??Z?????????????????????????????????????????????????????????Z???1/2?η????????Z???С?????????????С???????????????????????????????????????????????????????????????fluctuation??reptation????????????????????contour length?????????У?reptation time??????????е??????С??????????????????3??3.4??????? constrain release????????double reptation???????????tube?????????????У?????????reptation????????????target chain????????????????tube??chain??target chain???????????reptation?????????????Ч?????????reptation????? ??????modified????????????????????????????о?????????????????????? ????? touchhappy |
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