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這樣，每個sae2-配體的醇氧（圖2左中的O(2)、O(4)、O(6)和O(8)）都連接了兩個Mn(III)離子；另外，獨立的O2-（O(9)）離子橋聯(lián)三個Mn(III)離子；疊氮離子的N(5)橋聯(lián)了Mn(1)和Mn(4)離子，這三種橋聯(lián)形式共同連接，使配合物1形成了Mn4O4N的金剛烷結(jié)構(gòu)。配合物1結(jié)構(gòu)的顯著特點是其不存在任何對稱因素。 Furthermore, each alcohol oxygen (O(2), O(4), O(6) and O(8)) from sae2- ligand connect two Mn(III) ions, the independent O2-(O(9)) bridging three Mn(III) ions, N(5) from N3- bridging the Mn(1) and Mn(4) ions, the three bridge modes formed an adamantane-like Mn4O4N complex which have a significantly characterize that it does not exist any symmetry factors. |
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RXMCDM
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然memory: 金幣+15, 翻譯EPI+1, ★★★很有幫助 2014-01-11 09:35:40
然memory: 金幣+15, 翻譯EPI+1, ★★★很有幫助 2014-01-11 09:35:40
| Thus, two Mn (III) ions are connected to each sae2- ligand alcohol oxygen (left in Fig 2 ,O (2), O (4), O (6) ,and O (8)) .Furthermore, three Mn (III) ions are bridged by the independent O2-(O (9)) ions . The Mn (1) and Mn (4) ions are bridged by azide ion N (5) . The co-connection of the the three bridged links formed the Mn4O4N adamantane structure of complexe 1 . The distinctive feature of complexe 1 is that it has no any symmetrical structure element . |
2樓2014-01-10 20:56:45
【答案】應(yīng)助回帖
| So that, each alcohol oxygen of sae2-ligand(Left of Fig.2, O(2)、O(4)、O(6)andO(8)）are connected with two Mn(III) ions, in addition, the independent O2-（O(9)）ion is bridged with three Mn(III) ions, what’s more, Mn(1) and Mn(4) ions are bridged by azide ion N(5), the co-connection of such three bridged-link forged the complex 1 formed a adamantane structure, the distinctive characteristic of this structure is that it does not exist any symmetrical elements. |
3樓2014-01-10 22:09:01
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Thus, two Mn(III) ions are connected to each alcohol oxygen (O(2), O(4), O(6) and O(8) left in Fig 2) from sae2- ligand, furthermore, three Mn(III) ions are bridged by the independent O2-(O(9)), the Mn(1) and Mn(4) ions are linked to N(5) from N3-. The co-connection of the three bridging modes formed the Mn4O4N adamantane structure of complex 1 with a distinctive feature that it has no any symmetrical structure element. 你看我這樣修改好不好？ |
4樓2014-01-11 09:36:47
5樓2014-01-11 10:04:30
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