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[求助]
中譯英,兩句話
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| 在已知的單分子磁體中,基于H2sae及其衍生物的Mn4系列分子簇[183],由于其結(jié)構(gòu)中存在橋聯(lián)的鹵離子,所以其結(jié)構(gòu)具有一定的可調(diào)性。疊氮離子的橋聯(lián)方式非常靈活,其配合物的磁性也具有多變性。最近報道了將疊氮酸根引進(jìn)多核錳配合物的實例,值得一提的是其中一例配合物是單分子磁體 |
| among the known single molecular magnets, h2sae based and their derivative MN4 molecular clusters possess tunable structures via the bridged Cl-ions. As it is quite versatile to HN3 ion, their coordination compounds have variable magnetic properties. A case in point is, as recently reported, the introduciton of HN3 to Mn coordination compound can result in, among others, a single molecular magnet |
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The O-containing ligand used for the synthesis of polynuclear molecular clusters not only include classical carboxylic acid, but also include Schiff base ligand H2sae (H2sae=2-salicylidene-amino-1-ethanol), Phenolic ligands Hhmp (Hhmp = 2-hydroxymethylpyridine) and their derivatives, which manifest more diversity in assembly multinuclear complex because they both feature nitrogen and oxygen atoms 組裝這些多核分子簇的含氧配體除經(jīng)典的羧酸外,還包括希夫堿配體H2sae (H2sae = 2-salicylidene-amino-1-ethanol)及酚類配體Hhmp(Hhmp = 2-hydroxymethylpyridine)及其衍生物,這類配體同時含氮及氧,在組裝多核配合物方面具有很大的靈活性。 你幫我看下我這句英文表達(dá)的意思是否正確?謝謝了啊 |
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