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根據(jù)配合物1的晶體結(jié)構(gòu)參數(shù),Mn(1)-O(2)-Mn(2),Mn(3)-O(4)-Mn(2)和Mn(4)-O(8)-Mn(2)的鍵角很接近,可知Mn(1),Mn(3)和Mn(4)與Mn(2)之間的磁耦合常數(shù)J應(yīng)該很近,假定它們相等是合理的(J1)。 Based on the the crystal structure parameters of the complex 1, the bond angles of Mn(1)-O(2)-Mn(2) and Mn(3)-O(4)-Mn(2) are close to the bond angle of Mn(4)-O(8)-Mn(2), there are quite modest differences between the magnetic coupling constants of Mn(1), Mn(3) and Mn(4) respectively with Mn(2), hence, we hypothesize one J1 value between them is reasonable. |
榮譽版主 (知名作家)
快樂島、布吉島島主
| According to the crystal parameters, the bond angles of Mn (1)-O (2)-Mn (2), Mn (3)-O (4)-Mn (2) and Mn (3)-O (4)-Mn (2) are close to each other, which indicates that the magnetic coupling constants between Mn (1), Mn (3), Mn (4) and Mn(2) are comparable. Hence, it’s reasonable to suppose that they have equal J1 value. |
版主 (文壇精英)
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According to the crystal parameters, the bond angles of Mn (1)-O (2)-Mn (2), Mn (3)-O (4)-Mn (2) and Mn(4)-O(8)-Mn(2) are close to each other, which indicates that the magnetic coupling constants between Mn (1), Mn (3), Mn (4) and Mn(2) are comparable. Hence, it’s reasonable to suppose that they have equal J1 value. |

版主 (文壇精英)

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