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The complexes can be obtained in a one-pot reaction by conversion of the equatorial ligand with a slight excess of iron(II) acetate in the presence of the desired axial ligand. The term cooperativity describes the efficiency of the crystal lattice to transmit the geometry changes and electronic features that occur during a spin transition from one molecule to another. |
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The term cooperativity describes the efficiency of the crystal lattice to transmit the geometry changes and electronic features that occur during a spin transition from one molecule to another. 術語cooperativity(協(xié)同效應/協(xié)同性)描述晶格的傳輸效率,也就是由一個分子形成另一個分子的自旋轉換期間發(fā)生的幾何形狀變化和電子特性的傳輸效率。 |

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