| 2 | 1/1 | 返回列表 |
| 查看: 660 | 回復(fù): 1 | ||||
dk8060銀蟲 (小有名氣)
|
[求助]
單晶投稿---解析----求指教。! 已有1人參與
|
|
緊急求助,編輯后面這幾個(gè)問題到底是什么意思(投單晶文章,編輯回了一些問題,下面是不懂得問題,我該怎樣修改)?請(qǐng)高手指點(diǎn)啊!急死了: 5) Abstract: As mentioned in review 1, please give the graph-set notation for the main hydrogen-bonding ring motif. 6) Comment: The hydrogen bonding description is still inadequate. I assume that by "O1...N2", you actually mean "N2...H2a...O1". Please include Etter's graph-set notation. 7) Refinement: H atom description is still not sufficient. Riding H atoms have no SU on the distance(這里不懂)。. The N-H and O-H hydrogens are not even mentioned. 這是,該問題的原文: H atoms were placed in calculated positions withC---H = 0.97(1), 0.96 and 0.93(1) \%A for methylene, methyl and aryl H-atoms. All H atoms included in the final cycles of refinement using a riding model, with <i>U</i>~iso~(H) = 1.5<i>U</i>~eq~ (sp3) or 1.2<i>U</i>~eq~ of the carrier atoms. |
專家顧問 (著名寫手)
![]() |
專家經(jīng)驗(yàn): +759 |
|
我對(duì)你的問題逐條回復(fù),但僅供參考 5) Abstract: As mentioned in review 1, please give the graph-set notation for the main hydrogen-bonding ring motif. 這個(gè)問題是說你應(yīng)該對(duì)你化合物中出現(xiàn)的氫鍵環(huán)給出類似于R^n^~m~(A)的表示方法,其中n為氫鍵受體數(shù),上標(biāo),m為氫鍵給體數(shù),下標(biāo),A為氫鍵環(huán)數(shù)。 6) Comment: The hydrogen bonding description is still inadequate. I assume that by "O1...N2", you actually mean "N2...H2a...O1". Please include Etter's graph-set notation. 這個(gè)問題跟上一個(gè)類似,說你對(duì)氫鍵的描述不夠充分,說白了,就是描述的不夠深入,加一些有關(guān)氫鍵環(huán)表示的描述(同上)就行了。 7) Refinement: H atom description is still not sufficient. Riding H atoms have no SU on the distance(這里不懂)。. The N-H and O-H hydrogens are not even mentioned. 這是,該問題的原文: H atoms were placed in calculated positions withC---H = 0.97(1), 0.96 and 0.93(1) \%A for methylene, methyl and aryl H-atoms. All H atoms included in the final cycles of refinement using a riding model, with <i>U</i>~iso~(H) = 1.5<i>U</i>~eq~ (sp3) or 1.2<i>U</i>~eq~ of the carrier atoms. 這個(gè)問題你真不應(yīng)該犯這樣的錯(cuò)誤,通常情況下,理論加的氫是不應(yīng)該出現(xiàn)不確定度的,也就是說,0.97和0.93后不應(yīng)該跟括號(hào),而你文中又沒有給出N和O上的氫是用什么方法加的,所以審稿人才會(huì)提這樣的問題。因此,你需要在修改稿中加入N和O上的加氫方式。 基本就是這樣了,祝你好運(yùn)! |
| 2 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 一志愿南開大學(xué)0710生物學(xué)359求調(diào)劑 +3 | 兔兔兔111223314 2026-03-29 | 3/150 |
|
|---|---|---|---|---|
|
[考研] 275求調(diào)劑 +15 | Micky11223 2026-03-25 | 20/1000 |
|
|
[考研] 考研調(diào)劑 +7 | 小蠟新筆 2026-03-29 | 7/350 |
|
|
[考研] 一志愿211,335分,0856,求調(diào)劑院校和導(dǎo)師 +5 | 傾____蕭 2026-03-27 | 6/300 |
|
|
[考研] 298求調(diào)劑 +4 | 種圣賜 2026-03-28 | 4/200 |
|
|
[考研] 一志愿211 初試270分 求調(diào)劑 +8 | 谷雨上岸 2026-03-23 | 9/450 |
|
|
[考研] 學(xué)碩274求調(diào)劑 +9 | Li李魚 2026-03-26 | 9/450 |
|
|
[考研] 347求調(diào)劑 +3 | 山頂見α 2026-03-25 | 3/150 |
|
|
[考研] 藥學(xué)105500求調(diào)劑 +3 | Ssun。。 2026-03-28 | 3/150 |
|
|
[材料工程] 一志愿C9材料與化工專業(yè)總分300求調(diào)劑 +8 | 曼111 2026-03-24 | 9/450 |
|
|
[考研] 291求調(diào)劑 +6 | HanBeiNingZC 2026-03-24 | 6/300 |
|
|
[考研] 315分求調(diào)劑 +7 | 26考研上岸版26 2026-03-26 | 7/350 |
|
|
[考研] 266求調(diào)劑 +11 | 陽(yáng)陽(yáng)哇塞 2026-03-27 | 12/600 |
|
|
[考研] 求調(diào)劑,一志愿 南京航空航天大學(xué)大學(xué) ,080500材料科學(xué)與工程學(xué)碩 +4 | @taotao 2026-03-26 | 5/250 |
|
|
[考研] 317求調(diào)劑 +7 | 蛋黃咸肉粽 2026-03-26 | 7/350 |
|
|
[考研] 332求調(diào)劑 +6 | 032500 2026-03-25 | 6/300 |
|
|
[考研] 296求調(diào)劑 +4 | 汪?! 2026-03-25 | 7/350 |
|
|
[考研] 340求調(diào)劑 +5 | 話梅糖111 2026-03-24 | 5/250 |
|
|
[考研] 求調(diào)劑 +6 | 研研,接電話 2026-03-24 | 7/350 |
|
|
[考研] 一志愿吉大化學(xué)322求調(diào)劑 +4 | 17501029541 2026-03-23 | 6/300 |
|