 |
 |
 |
 |
 |
 |
||
 |
 |
 |
 |
 |
| 2 | 1/1 | 返回列表 |
| 查看: 619 | 回復(fù): 1 | |||
11900490木蟲 (知名作家)
|
[交流]
Leonard R. MacGillivray 已有1人參與
|
 http://www.chem.uiowa.edu/people/leonard-r-macgillivray  http://pubs.rsc.org/en/Content/A ... 51073E#!divAbstract Leonard R. MacGillivray Leonard R. MacGillivray Professor Phone: 319-335-3504 Office: E555 CB Email: len-macgillivray@uiowa.edu CV: View/Download File Group Homepage: http://www.chem.uiowa.edu/macgillivray-research-group Divisions: Organic Chemistry Biosketch: B.S., Saint Mary's University (1994) Ph.D., University of Missouri-Columbia (1998) Research Associate, Steacie Institute for Molecular Sciences, National Research Council of Canada (1998-2000) Adjunct Research Professor, Ottawa-Carleton Chemistry Institute (1999-2000) Keywords: Molecular recognition; solid state organic and inorganic chemistry; crystal photochemistry; nanotechnology. Synthesis of porous molecular solids and nanometer scale molecular structures for applications in separations, catalysis, and molecular switching. Organic solid state synthesis by design. Research Interests: Whereas more traditional approaches to chemical synthesis have focused upon atoms and molecules individually, our research encompasses understanding principles that govern the effects of intermolecular interactions (e.g. hydrogen bonds) on the structure and properties of assemblies of atoms and molecules in the field of supramolecular chemistry. The structure of DNA and ability of enzymes to catalyze chemical reactions are examples from biochemistry that are regulated by such interactions and we address whether such forces may be used to confront long-standing problems with new perspectives or design new molecules and materials with unique properties. Materials Design. It is well established that molecular approaches to crystal structure design can lead to new materials with desirable properties (e.g. optical). Despite this realization, an insufficient knowledge of factors that dictate crystal packing has hindered chemists from designing molecules that assemble to form functional solids, a priori, with predictable properties. This problem of crystal structure design, referred to as a problem of crystal engineering, is similar to solution phase organic synthesis in that chemists must plan routes, involving structural units known as synthons, to targeted, functional molecular systems. However, whereas solution phase organic synthesis is at a stage where synthetic routes are being reexamined to reduce steps for atom economy, the field of rational solid state design is at a stage where synthons are beginning to be identified. Of the properties that may be exploited for the design of molecular solids, it is solid state reactivity, in the form of bimolecular reactions, that we are studying. Such an approach to synthesis holds great promise for the designed, solvent-free synthesis of molecules, and materials, available either in low yields, as part of mixtures, or are completely inaccessible in the liquid phase. Unfortunately, however, most approaches to synthesis in the solid state are generally unreliable such that reaction homology, a concept central to the development of solution phase molecular synthesis, has been achieved with limited success. We are addressing this problem of reaction homology, using an approach that controls reactivity in solids by employing molecules that serve, via molecular recognition processes based on hydrogen bonds, as linear templates (see Figure 1), with the prospect that a reliable method for conducting reactions in the solid state will permit us to establish novel applications for the reactants (e.g. green chemistry), products (e.g. nanostructures), and materials (e.g. molecular devices). |
回復(fù)此樓» 猜你喜歡
中南大學(xué)化學(xué)化工學(xué)院易小藝教授課題組招收2026級博士研究生（第二輪）
已經(jīng)有0人回復(fù)
-
求助
已經(jīng)有1人回復(fù)
-
無機(jī)化學(xué)論文潤色/翻譯怎么收費(fèi)?
已經(jīng)有213人回復(fù)
-
0703化學(xué)26考研調(diào)劑，一志愿南昌大學(xué)
已經(jīng)有2人回復(fù)
-
有沒有化學(xué)、材料專業(yè)的同學(xué)需要調(diào)劑 考慮天津高效的可以郵件或者私信
已經(jīng)有1人回復(fù)
-
26年博士招生
已經(jīng)有16人回復(fù)
-
江西理工大學(xué)功能晶態(tài)材料方向劉遂軍課題組招收2026年秋季入學(xué)博士研究生
已經(jīng)有10人回復(fù)
-
寧夏大學(xué)團(tuán)簇新材料團(tuán)隊(duì)招收材料/化學(xué)/化工專業(yè)博士生
已經(jīng)有0人回復(fù)
-
MIL-101有單晶樣品嗎
已經(jīng)有1人回復(fù)
-
西北大學(xué)26年化學(xué)博士招生
已經(jīng)有3人回復(fù)
-
收調(diào)劑研究生
已經(jīng)有2人回復(fù)
» 本主題相關(guān)價值貼推薦，對您同樣有幫助:
- 乙烯基吡啶+銀 進(jìn)行[2+2]光化學(xué)反應(yīng)
已經(jīng)有12人回復(fù)
- 求各位大神推薦關(guān)于金屬有機(jī)材料MOFs的基礎(chǔ)書籍或文獻(xiàn)
已經(jīng)有5人回復(fù)
- 無奈，不懂化學(xué)的領(lǐng)導(dǎo)，讓我用兩個化合物一起結(jié)晶，求支持
已經(jīng)有17人回復(fù)
- 有沒有朋友做過β-環(huán)糊精包結(jié)小分子，培養(yǎng)單晶的��？拜求高手指點(diǎn)迷津啊~~
已經(jīng)有7人回復(fù)
2樓2014-03-28 21:05:16
相關(guān)版塊跳轉(zhuǎn)
我要訂閱樓主 11900490 的主題更新
| 2 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 材料 271求調(diào)劑 +3 | 展信悅_ 2026-03-21 | 3/150 |
|
|---|---|---|---|---|
|
[考研] 材料工程（專）一志愿985 初試335求調(diào)劑 +3 | hiloiy 2026-03-17 | 4/200 |
|
|
|
[考研] 083200學(xué)碩321分一志愿暨南大學(xué)求調(diào)劑 +3 | innocenceF 2026-03-17 | 3/150 |
|
|
|
[考研] 化學(xué)求調(diào)劑 +4 | 臨澤境llllll 2026-03-17 | 5/250 |
|
|
|
[考研] 材料專業(yè)求調(diào)劑 +6 | hanamiko 2026-03-18 | 6/300 |
|
|
|
[考研] 304求調(diào)劑 +7 | 司空. 2026-03-18 | 7/350 |
|
|
|
[考研] 藥學(xué)383 求調(diào)劑 +3 | 藥學(xué)chy 2026-03-15 | 5/250 |
|
|
|
[考研] 一志愿華中農(nóng)業(yè)071010，總分320求調(diào)劑 +3 | 困困困困坤坤 2026-03-20 | 3/150 |
|
|
|
[考研] 085410人工智能專碩317求調(diào)劑（0854都可以） +4 | xbxudjdn 2026-03-18 | 4/200 |
|
|
|
[考研] 生物學(xué)調(diào)劑招人�。�！ +3 | 山海天嵐 2026-03-17 | 4/200 |
|
|
|
[考博] 申博26年 +3 | 八6八68 2026-03-19 | 3/150 |
|
|
|
[考研] 梁成偉老師課題組歡迎你的加入 +9 | 一鴨鴨喲 2026-03-14 | 11/550 |
|
|
|
[考研] 材料工程專碩調(diào)劑 +5 | 204818@lcx 2026-03-17 | 6/300 |
|
|
|
[考研] 293求調(diào)劑 +11 | zjl的號 2026-03-16 | 16/800 |
|
|
|
[考研] 考研求調(diào)劑 +3 | 橘頌. 2026-03-17 | 4/200 |
|
|
|
[考研] 考研化學(xué)學(xué)碩調(diào)劑，一志愿985 +4 | 張vvvv 2026-03-15 | 6/300 |
|
|
|
[考研] 考研調(diào)劑 +3 | 淇ya_~ 2026-03-17 | 5/250 |
|
|
|
[考研] 0703化學(xué)調(diào)劑 290分有科研經(jīng)歷，論文在投 +7 | 膩膩gk 2026-03-14 | 7/350 |
|
|
|
[考研] 326求調(diào)劑 +3 | mlpqaz03 2026-03-15 | 3/150 |
|
|
|
[考研] 288求調(diào)劑 +4 | 奇點(diǎn)0314 2026-03-14 | 4/200 |
|