具有空心結(jié)構(gòu)的介孔材料因其巨大的比表面積在能源、催化等領域有著廣泛的應用。本文介紹了近年來空心結(jié)構(gòu)介孔材料的大量文獻的最新研究進展,為研究該領域提供了很好的指導。題目為Hollow-Structured Mesoporous Materials: Chemical Synthesis, Functionalization and Applications
Keywords:
hollow materials;mesoporous materials;core–shell materials;synthesis;applications
Hollow-structured mesoporous materials (HMMs), as a kind of mesoporous material with unique morphology, have been of great interest in the past decade because of the subtle combination of the hollow architecture with the mesoporous nanostructure. Benefitting from the merits of low density, large void space, large specific surface area, and, especially, the good biocompatibility, HMMs present promising application prospects in various fields, such as adsorption and storage, confined catalysis when catalytically active species are incorporated in the core and/or shell, controlled drug release, targeted drug delivery, and simultaneous diagnosis and therapy of cancers when the surface and/or core of the HMMs are functionalized with functional ligands and/or nanoparticles, and so on. In this review, recent progress in the design, synthesis, functionalization, and applications of hollow mesoporous materials are discussed. Two main synthetic strategies, soft-templating and hard-templating routes, are broadly sorted and described in detail. Progress in the main application aspects of HMMs, such as adsorption and storage, catalysis, and biomedicine, are also discussed in detail in this article, in terms of the unique features of the combined large void space in the core and the mesoporous network in the shell. Functionalization of the core and pore/outer surfaces with functional organic groups and/or nanoparticles, and their performance, are summarized in this article. Finally, an outlook of their prospects and challenges in terms of their controlled synthesis and scaled application is presented.![Adv. Mater.最新綜述:空心結(jié)構(gòu)介孔材料---化學合成、功能化及應用]()
Hollow-Structured Mesoporous Materials: Chemical Synthesis, Functionalization and Applications.jpg |